GLYOXAL (liquid) 40% For Synthesis

GLYOXAL (liquid) 40% For Synthesis

Synonyms : Ethanedial; Oxalaldehyde

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : GLYOXAL (liquid) 40%
Catalogue No. : AL2320 Product form : Substance
CAS Number : 107-22-2 EC Number :
Grade : EC Index Number :
Chemical Formula : C2H2O2 HSN Code : 29121930
Synonyms : Ethanedial
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.),
Category 3
H331
Skin corrosion/irritation,
Category 2
H315
Serious eye damage/eye
irritation, Category 2
H319
Skin sensitisation, H317
category 1B
Germ cell mutagenicity,
Category 2
H341
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xi; R36/37/38
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS08GHS08
Signal word (CLP) : Danger
Hazard statements (CLP) : H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H331 - Toxic if inhaled.
H341 - Suspected of causing genetic defects.
Precautionary statements (CLP) : P261 - Avoid breathing dust, fume, gas, vapours, spray, mist.
P280 - Wear protective clothing, protective gloves, eye protection, face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P311 - Call a POISON CENTER/doctor
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : GLYOXAL 40% FOR SYNTHESIS
CAS No. : 107-22-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
First-aid measures after skin contact : Wash with plenty of water/…. Wash contaminated clothing before reuse. Get
medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : May cause an allergic skin reaction. Suspected of causing genetic defects.
Symptoms/effects after inhalation : Toxic if inhaled.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Do not breathe vapours. Avoid contact with skin and eyes. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid
Molecular mass : 58.04 g/mol
Colour : Clear Colorless.
Odour : characteristic odour.
Odour threshold : No data available
pH value : Neutral
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : 51 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 17535 mm Hg (at 20°C)
Relative vapour density at 20°C : 0.62
Density : 1.27 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Inhalation: Toxic if inhaled.
Skin corrosion/irritation : Causes skin irritation.
pH: Neutral
Serious eye damage/irritation : Causes serious eye irritation.
pH: Neutral
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Additional Info : No additional information available

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : Not applicable
UN-No. (IMDG) : Not applicable
UN-No. (IATA) : Not applicable
UN-No. (ADN) : Not applicable
UN-No. (RID) : Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) : Not applicable
Proper Shipping Name (IMDG) : Not applicable
Proper Shipping Name (IATA) : Not applicable
Proper Shipping Name (ADN) : Not applicable
Proper Shipping Name (RID) : Not applicable
Transport document description (ADR) : Not applicable
Transport document description (IMDG) : Not applicable
Transport document description (IATA) : Not applicable
Transport document description (ADN) : Not applicable
Transport document description (RID) : Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : Not applicable
IMDG
Transport hazard class(es) : Not applicable
IATA
Transport hazard class(es) : Not applicable
ADN
Transport hazard class(es) : Not applicable
RID
Transport hazard class(es) : Not applicable
14.4. Packing group
Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
GLYOXAL 40% FOR SYNTHESIS is not on the REACH Candidate List
GLYOXAL 40% FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 1130)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Muta. 2 Germ cell mutagenicity, Category 2
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1B Skin sensitisation, category 1B
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H341 Suspected of causing genetic defects.
R36/37/38 Irritating to eyes, respiratory system and skin
Xi Irritant