LEAD CHROMATE AR

LEAD CHROMATE AR

Synonyms : Lead(II) chromate

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : LEAD CHROMATE AR
Catalogue No. : AL2699 Product form : Substance
CAS Number : 7758-97-6 EC Number : 231-846-0
Grade : EC Index Number : 082-004-00-2
Chemical Formula : HSN Code : 29152990
Synonyms : Lead(II) chromate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Carcinogenicity, Category
1B
H350
Reproductive toxicity,
Category 1A
H360D
Reproductive toxicity,
Category 2
H361f
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.2; R45
Repr.Cat.1; R61
Repr.Cat.3; R62
N; R50/53
R33
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS08GHS08 GHS09GHS09
Signal word (CLP) : -
Hazard statements (CLP) : H350 - May cause cancer.
H360D - May damage the unborn child.
H361f - Suspected of damaging fertility.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P273 - Avoid release to the environment.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P501 - Dispose of contents/container to hazardous or special waste collection point,
in accordance with local, regional, national and/or international regulation
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : LEAD CHROMATE AR
CAS No. : 7758-97-6
EC Index No. : 082-004-00-2
EC No. : 231-846-0
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical
advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : May cause cancer. Suspected of damaging fertility. May damage the unborn child.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Avoid contact with skin, eyes and clothing.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 323.18 g/mol
Colour : White powder.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 8440 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 6.3 g/cm3
Solubility : Water: Negligible
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : May cause cancer.
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Additional information : There are potential chronic health effects to consider

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : LEAD CHROMATE AR (7758-97-6) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
LEAD CHROMATE AR (7758-97-6)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3077
UN-No. (IMDG) : 3077
UN-No. (IATA) : 3077
UN-No. (ADN) : 3077
UN-No. (RID) : 3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (ADN) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 9
Danger labels : 9
IMDG
Transport hazard class(es) : 9
Danger labels : 9
IATA
Transport hazard class(es) : 9
Danger labels : 9
ADN
Transport hazard class(es) : 9
Danger labels : 9
RID
Transport hazard class(es) : 9
Danger labels : 9
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M7
Special provisions (ADR) : 274, 335, 375, 601
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : PP12, B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1, BK1, BK2, BK3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV, LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V13
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13
Hazard identification number (Kemler No.) : 90
Orange plates :
Tunnel restriction code (ADR) : -
EAC code : 2Z
- Transport by sea
Special provisions (IMDG) : 274, 335, 966, 967, 969
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : LP02, P002
Special packing provisions (IMDG) : PP12
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : BK1, BK2, BK3, T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW23
MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y956
PCA limited quantity max net quantity
(IATA)
: 30kgG
PCA packing instructions (IATA) : 956
PCA max net quantity (IATA) : 400kg
CAO packing instructions (IATA) : 956
CAO max net quantity (IATA) : 400kg
Special provisions (IATA) : A97, A158, A179, A197
ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M7
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T* B**
Equipment required (ADN) : PP, A
Number of blue cones/lights (ADN) : 0
Additional requirements/Remarks (ADN) : * Only in the molten state. ** For carriage in bulk see also 7.1.4.1. ** * Only in the
case of transport in bulk.
- Rail transport
Classification code (RID) : M7
Special provisions (RID) : 274, 335, 375, 601
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : PP12, B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1, BK1, BK2, BK3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV, LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W13
Special provisions for carriage – Bulk
(RID)
: VC1, VC2
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Lead chromate is on the REACH Candidate List
Lead chromate is on the REACH Annex XIV List:
Authorisation number Sunset date REACH authorisation exemptions
21/05/2015
15.1.2. National regulations
Germany
AwSV/VwVwS Annex Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to
AwSV; ID No. 7885)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : LEAD CHROMATE AR is listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen -Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: LEAD CHROMATE AR is listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen - Ontwikkeling
: LEAD CHROMATE AR is listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Carc. 1B Carcinogenicity, Category 1B
Repr. 1A Reproductive toxicity, Category 1A
Repr. 2 Reproductive toxicity, Category 2
H350 May cause cancer.
H360D May damage the unborn child.
H361f Suspected of damaging fertility.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
R33 Danger of cumulative effects
R45 May cause cancer
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R61 May cause harm to the unborn child
R62 Possible risk of impaired fertility
N Dangerous for the environment