NAPHTHALENE For Synthesis |
| Synonyms : White tar; Naphthalin; Camphor tar |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | NAPHTHALENE balls (for synthesis) | ||
| Catalogue No. : | AL3161 | Product form : | Substance |
| CAS Number : | 91-20-3 | EC Number : | 202-049-5 |
| Grade : | EC Index Number : | 601-052-00-2 | |
| Chemical Formula : | HSN Code : | 29029040 | |
| Synonyms : | White tar; Naphthalin; Camphor tar | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Flammable solids, Category 1 H228 Acute toxicity (oral), Category 4 H302 Carcinogenicity, Category 2 H351 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 Xn; R22 N; R50/53 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS07
 GHS08
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H228 - Flammable solid H302 - Harmful if swallowed H351 - Suspected of causing cancer H410 - Very toxic to aquatic life with long lasting effects |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use P308+P313 - IF exposed or concerned: Get medical advice/attention P330 - Rinse mouth P370+P378 - In case of fire: Use ... for extinction P501 - Dispose of contents/container to ... |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | NAPHTHALENE FOR SYNTHESIS | ||
| CAS No. : | 91-20-3 | ||
| EC Index No. : | 601-052-00-2 | ||
| EC No. : | 202-049-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries after ingestion : Harmful if swallowed. Chronic symptoms : Suspected carcinogen. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Dry chemical, CO2, dry sand, or alcohol-resistant foam. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | |
| Explosion hazard : | |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Very toxic to aquatic life with long lasting effects. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear appropriate mask |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 128.17 g/mol |
| Colour : | White scales. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 77 °C |
| Freezing point : | No data available |
| Boiling point : | 218 °C |
| Flash point : | 80 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 0.03 hPa at 20°C |
| Relative vapour density at 20°C : | 4.4 |
| Density : | 1.2 g/cm3 |
| Solubility : | Water: Insoluble in water |
| Log Pow : | 3.3 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.009 - 0.059 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Flammable solid. | |
10.2 Chemical stability |
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| Stable under normal conditions of use. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Not classified |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
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| Persistence - degradability : | NAPHTHALENE FOR SYNTHESIS (91-20-3) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | NAPHTHALENE FOR SYNTHESIS (91-20-3) Log Pow 3.3 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1334 |
| UN-No. (IMDG) : | 1334 |
| UN-No. (IATA) : | 1334 |
| UN-No. (ADN) : | 1334 |
| UN-No. (RID) : | 1334 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | NAPHTHALENE, CRUDE |
| Proper Shipping Name (IMDG) : | NAPHTHALENE, CRUDE |
| Proper Shipping Name (IATA) : | NAPHTHALENE, CRUDE |
| Proper Shipping Name (ADN) : | NAPHTHALENE, CRUDE |
| Proper Shipping Name (RID) : | NAPHTHALENE, CRUDE |
| Transport document description (ADR) : | UN 1334, NAPHTHALENE, CRUDE, 4.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 1334, NAPHTHALENE, CRUDE, 4.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 1334, NAPHTHALENE, CRUDE, 4.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 1334, NAPHTHALENE, CRUDE, 4.1, III ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 1334, NAPHTHALENE, CRUDE, 4.1, III ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1 
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| IMDG | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
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| IATA | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
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| ADN | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
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| RID | |
| Transport hazard class(es) : | 4.1 |
| Danger labels : | 4.1
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : F1 Special provision (ADR) : 501 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1, BK1, BK2 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP1 Hazard identification number (Kemler No.) : 40 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1Z |
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| - Transport by sea | |
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Special provision (IMDG) : 948, 967 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002, LP02 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1, BK2, BK3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-G Stowage category (IMDG) : A Stowage and handling (IMDG) : SW23 MFAG-No : 133 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y443 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 446 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 449 CAO max net quantity (IATA) : 100kg ERG code (IATA) : 3L |
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| - Inland waterway transport | |
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Classification code (ADN) : F1 Special provisions (ADN) : 501 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Carriage permitted (ADN) : B Equipment required (ADN) : PP Provisions for carriage in bulk (ADN) : CO01 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : F1 Special provision (RID) : 501 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1, BK1, BK2 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W1 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP1 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 40 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions NAPHTHALENE FOR SYNTHESIS is not on the REACH Candidate List NAPHTHALENE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 269) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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