SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	WIJ'S solution
Catalogue No. :	AL4789	Product form :	Mixture
CAS Number :	7790-99-0	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	38220090
Synonyms :	Wij's Solution
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS08
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H314 - Causes severe skin burns and eye damage. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H351 - Suspected of causing cancer.
Precautionary statements (CLP) :	P280 - Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		7790-99-0
3.2. Mixture
Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acetic acid	(CAS-No.) 64-19-7 (EC-No.) 200-580-7 (EC Index-No.) 607-002-00-6	98.6	Skin Corr. 1A, H314 Eye Dam. 1, H318 Flam. Liq. 3, H226 Acute Tox. 4 (Inhalation), H332
Iodine	(CAS-No.) 7553-56-2 (EC-No.) 231-442-4 (EC Index-No.) 053-001-00-3	1.3	Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Aquatic Acute 1, H400
Chlorine	(CAS-No.) 7782-50-5 (EC-No.) 231-959-5 (EC Index-No.) 017-001-00-7	0.1	Acute Tox. 3 (Inhalation), H331 Eye Irrit. 2, H319 Skin Irrit. 2, H315 STOT SE 3, H335 Aquatic Acute 1, H400
Full text of H-statements: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
First-aid measures after skin contact :	Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. Chronic symptoms : May cause cancer.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area. Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures :	Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations.
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear appropriate mask

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Dark orange to brown.
Odour :	No data available
Odour threshold :	No data available
pH value :	2.4
Relative evaporation rate (butylacetate=1) :	0.97
Melting point :	No data available
Freezing point :	No data available
Boiling point :	118 °C
Flash point :	40 °C
Auto-ignition temperature :	427 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	11 mm Hg at 20°C
Relative vapour density at 20°C :	2.1
Density :	1.05 g/cm3
Solubility :	Water: Infinitely soluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Open flame. Overheating. Heat.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Causes severe skin burns and eye damage. pH: 2.4
Serious eye damage/irritation :	Serious eye damage, category 1, implicit pH: 2.4
Respiratory or skin sensitisation :	May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer.
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	2920
UN-No. (IMDG) :	2920
UN-No. (IATA) :	2920
UN-No. (ADN) :	2920
UN-No. (RID) :	2920
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Proper Shipping Name (IMDG) :	CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Proper Shipping Name (IATA) :	CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Proper Shipping Name (ADN) :	CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Proper Shipping Name (RID) :	CORROSIVE LIQUID, FLAMMABLE, N.O.S.
Transport document description (ADR) :	UN 2920, CORROSIVE LIQUID, FLAMMABLE, N.O.S., 8 (3), II
Transport document description (IMDG) :	UN 2920, CORROSIVE LIQUID, FLAMMABLE, N.O.S., 8 (3), II
Transport document description (IATA) :	UN 2920, CORROSIVE LIQUID, FLAMMABLE, N.O.S., 8 (3), II
Transport document description (ADN) :	UN 2920, CORROSIVE LIQUID, FLAMMABLE, N.O.S., 8 (3), II
Transport document description (RID) :	UN 2920, CORROSIVE LIQUID, FLAMMABLE, N.O.S., 8 (3), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IMDG
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
IATA
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
ADN
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
RID
Transport hazard class(es) :	8 (3)
Danger labels :	8, 3
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : CF1 Special provisions (ADR) : 274 Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T11 Portable tank and bulk container special provisions (ADR) : TP2, TP27 Tank code (ADR) : L4BN Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 83 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3W APP code : A(fl)
- Transport by sea
Special provisions (IMDG) : 274 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T11 Tank special provisions (IMDG) : TP2, TP27 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : C Stowage and handling (IMDG) : SW1, SW2 Properties and observations (IMDG) : Causes burns to skin, eyes and mucous membranes. MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8F
- Inland waterway transport
Classification code (ADN) : CF1 Special provisions (ADN) : 274 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : CF1 Special provisions (RID) : 274 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T11 Portable tank and bulk container special provisions (RID) : TP2, TP27 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 83
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : None of the components are listed
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements: Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Carc. 2 Carcinogenicity, Category 2 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Resp. Sens. 1 Respiratory sensitisation, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H400 Very toxic to aquatic life.