p-CRESOL For Synthesis

p-CRESOL For Synthesis

Synonyms : 4-Methylphenol

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : p-CRESOL (for synthesis)
Catalogue No. : AL1552 Product form : Substance
CAS Number : 106-44-5 EC Number :
Grade : EC Index Number :
Chemical Formula : C7H8O HSN Code : 29071210
Synonyms : 4-Methylphenol
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal),
Category 3
H311
Acute toxicity (oral),
Category 3
H301
Skin corrosion/irritation,
Category 1B
H314
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R24/25
C; R34
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS05GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H301+H311 - Toxic if swallowed or in contact with skin
H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protection, face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER or doctor.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : p-CRESOL FOR SYNTHESIS
CAS No. : 106-44-5
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Wash
contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Immediately call a POISON CENTER/doctor. Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after skin contact : Toxic in contact with skin.
Symptoms/effects after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 108.14 g/mol
Colour : Light yellowish.
Odour : phenolic odor.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 31 - 34 °C
Freezing point : No data available
Boiling point : 201 °C
Flash point : 86 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 1.3 hPa at 20°C
Relative vapour density at 20°C : 3.72
Solubility : Water: Slightly soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Toxic in contact with skin. Oral: Toxic if swallowed.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3455
UN-No. (IMDG) : 3455
UN-No. (IATA) : 3455
UN-No. (ADN) : 3455
UN-No. (RID) : 3455
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CRESOLS, SOLID
Proper Shipping Name (IMDG) : CRESOLS, SOLID
Proper Shipping Name (IATA) : CRESOLS, SOLID
Proper Shipping Name (ADN) : CRESOLS, SOLID
Proper Shipping Name (RID) : CRESOLS, SOLID
Transport document description (ADR) : UN 3455, CRESOLS, SOLID, 6.1 (8), II
Transport document description (IMDG) : UN 3455, CRESOLS, SOLID, 6.1 (8), II
Transport document description (IATA) : UN 3455, CRESOLS, SOLID, 6.1 (8), II
Transport document description (ADN) : UN 3455, CRESOLS, SOLID, 6.1 (8), II
Transport document description (RID) : UN 3455, CRESOLS, SOLID, 6.1 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1 (8)
Danger labels : 6.1, 8
IMDG
Transport hazard class(es) : 6.1 (8)
Danger labels : 6.1, 8
IATA
Transport hazard class(es) : 6.1 (8)
Danger labels : 6.1, 8
ADN
Transport hazard class(es) : 6.1 (8)
Danger labels : 6.1, 8
RID
Transport hazard class(es) : 6.1 (8)
Danger labels : 6.1, 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TC2
Limited quantities (ADR) : 500g
Excepted quantities (ADR) : E4
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T3
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAH, L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V11
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9, S19
Hazard identification number (Kemler No.) : 68
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : 2X
- Transport by sea
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B21, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-B
Stowage category (IMDG) : B
Properties and observations (IMDG) : Light yellow solid. Soluble in water. Melting points of CRESOLS: ortho- CRESOL:
30°C, para-CRESOL: 35°C. Toxic if swallowed, by skin contact or by
inhalation. Cause burns to skin, eyes and mucous membranes.
MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E4
PCA Limited quantities (IATA) : Y644
PCA limited quantity max net quantity
(IATA)
: 1kg
PCA packing instructions (IATA) : 668
PCA max net quantity (IATA) : 15kg
CAO packing instructions (IATA) : 675
CAO max net quantity (IATA) : 50kg
ERG code (IATA) : 6C
- Inland waterway transport
Classification code (ADN) : TC2
Special provisions (ADN) : 802
Limited quantities (ADN) : 500 g
Excepted quantities (ADN) : E4
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TC2
Excepted quantities (RID) : E4
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T3
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAH, L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W11
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE9
Hazard identification number (RID) : 68
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
p-CRESOL FOR SYNTHESIS is not on the REACH Candidate List
p-CRESOL FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, low hazard to water (Classification according to AwSV;
ID No. 1592)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Skin Corr. 1B Skin corrosion/irritation, Category 1B
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
R24/25 Toxic in contact with skin and if swallowed
R34 Causes burns
C Corrosive
T Toxic