PHENYL HYDRAZINE For Synthesis |
| Synonyms : Hydrazinobenzene |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | PHENYL HYDRAZINE (for synthesis) | ||
| Catalogue No. : | AL3507 | Product form : | Substance |
| CAS Number : | 100-63-0 | EC Number : | 202-873-5 |
| Grade : | EC Index Number : | 612-023-00-9 | |
| Chemical Formula : | HSN Code : | 29280090 | |
| Synonyms : | Hydrazinobenzene | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Carcinogenicity, Category 1B H350 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Specific target organ toxicity Repeated exposure, Category 1 H372 Germ cell mutagenicity, Category 2 H341 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Sensitisation Skin, category 1 H317 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.2; R45 Muta.Cat.3; R68 T; R23/24/25 T; R48/23/24/25 Xi; R36/38 R43 N; R50 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
 GHS09
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| Signal word (CLP) : | - |
| Hazard statements (CLP) : | H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation H341 - Suspected of causing genetic defects H350 - May cause cancer H372 - Causes damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | PHENYL HYDRAZINE FOR SYNTHESIS | ||
| CAS No. : | 100-63-0 | ||
| EC Index No. : | 612-023-00-9 | ||
| EC No. : | 202-873-5 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. |
| First-aid measures after skin contact : | Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Specific measures (see ... on this label). Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). If skin irritation or rash occurs: |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this label). |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : Suspected of causing genetic defects. May cause cancer. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : May cause an allergic skin reaction. May cause respiratory irritation. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a wellventilated a |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid Colour |
| Colour : | Pale yellow. |
| Odour : | faint aromatic odor. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 18 - 21 |
| Freezing point : | No data available |
| Boiling point : | 238 - 241 |
| Flash point : | 89 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 1 mm Hg at 71.80C |
| Relative vapour density at 20°C : | 3.7 |
| Density : | 1.098 g/cm3 |
| Solubility : | Water: Slightly soluble in hot water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.011 vol % |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Suspected of causing genetic defects. |
| Carcinogenicity : | May cause cancer. |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | May cause respiratory irritation. |
| Specific target organ toxicity (repeated exposure) : | Causes damage to organs through prolonged or repeated exposure. |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | Ecology - water : Very toxic to aquatic life. |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 2572 |
| UN-No. (IMDG) : | 2572 |
| UN-No. (IATA) : | 2572 |
| UN-No. (ADN) : | 2572 |
| UN-No. (RID) : | 2572 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | PHENYLHYDRAZINE |
| Proper Shipping Name (IMDG) : | PHENYLHYDRAZINE |
| Proper Shipping Name (IATA) : | PHENYLHYDRAZINE |
| Proper Shipping Name (ADN) : | PHENYLHYDRAZINE |
| Proper Shipping Name (RID) : | PHENYLHYDRAZINE |
| Transport document description (ADR) : | UN 2572, PHENYLHYDRAZINE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 2572, PHENYLHYDRAZINE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 2572, PHENYLHYDRAZINE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 2572, PHENYLHYDRAZINE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 2572, PHENYLHYDRAZINE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
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| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : T1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3X |
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| - Transport by sea | |
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Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 MFAG-No : 153 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L ERG code (IATA) : 6L |
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| - Inland waterway transport | |
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Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2 |
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| - Rail transport | |
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Classification code (RID) : T1 Limited quantities (RID) : 100ml Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions PHENYL HYDRAZINE FOR SYNTHESIS is not on the REACH Candidate List PHENYL HYDRAZINE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 1484) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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