SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	PHOSPHOROUS PENTASULPHIDE
Catalogue No. :	AL3548	Product form :	Substance
CAS Number :	1314-80-3	EC Number :	215-242-4
Grade :		EC Index Number :	015-104-00-1
Chemical Formula :	P2S5	HSN Code :	28139090
Synonyms :	Phosphorus(V) sulfide
Chemical Structure :	P2S5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable solids, Category 1 H228 Substances and Mixtures which, in contact with water, emit flammable gases, Category 1 H260 Acute toxicity (oral), Category 4 H302 Acute toxicity (inhal.), Category 4 H332 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11 Xn; R20/22 N; R50 R29 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H228 - Flammable solid. H260 - In contact with water releases flammable gases which may ignite spontaneously. H302+H332 - Harmful if swallowed or if inhaled H400 - Very toxic to aquatic life.
Precautionary statements (CLP) :	P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P223 - Do not allow contact with water. P231+P232 - Handle under inert gas. Protect from moisture. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P370+P378 - In case of fire: Use ... to extinguish.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		PHOSPHORUS PENTASULFIDE FOR SYNTHESIS
CAS No. :		1314-80-3
EC Index No. :		015-104-00-1
EC No. :		215-242-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Take off contaminated clothing. Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : Harmful if inhaled. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Dry powder.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Flammable solid.
Explosion hazard :	May form flammable/explosive vapour-air mixture. Reactivity in case of fire : Reacts violently with water (moisture): release of toxic/combustible gases/vapours.
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Large spills: scoop solid spill into closing containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling :	No open flames. No smoking.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	222.27 g/mol
Colour :	Yellow.
Odour :	stench.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	280 - 284 °C
Freezing point :	No data available
Boiling point :	514 °C
Flash point :	No data available
Auto-ignition temperature :	1420 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable solid.
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	2.03 g/cm3
Solubility :	Water: Insoluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Flammable solid. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
Highly reactive material. Contact with water liberates toxic gas.
10.4 Conditions to avoid
Do not allow contact with water. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Inhalation: Harmful if inhaled.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1340
UN-No. (IMDG) :	1340
UN-No. (IATA) :	1340
UN-No. (ADN) :	1340
UN-No. (RID) :	1340
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	PHOSPHORUS PENTASULPHIDE
Proper Shipping Name (IMDG) :	PHOSPHORUS PENTASULPHIDE
Proper Shipping Name (IATA) :	PHOSPHORUS PENTASULPHIDE
Proper Shipping Name (ADN) :	PHOSPHORUS PENTASULPHIDE
Proper Shipping Name (RID) :	PHOSPHORUS PENTASULPHIDE
Transport document description (ADR) :	UN 1340, PHOSPHORUS PENTASULPHIDE, 4.3 (4.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1340, PHOSPHORUS PENTASULPHIDE, 4.3 (4.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1340, PHOSPHORUS PENTASULPHIDE, 4.3 (4.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1340, PHOSPHORUS PENTASULPHIDE, 4.3 (4.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1340, PHOSPHORUS PENTASULPHIDE, 4.3 (4.1), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	4.3 (4.1)
Danger labels :	4.3, 4.1
IMDG
Transport hazard class(es) :	4.3 (4.1)
Danger labels :	4.3, 4.1
IATA
Transport hazard class(es) :	4.3 (4.1)
Danger labels :	4.3, 4.1
ADN
Transport hazard class(es) :	4.3 (4.1)
Danger labels :	4.3, 4.1
RID
Transport hazard class(es) :	4.3 (4.1)
Danger labels :	4.3, 4.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : WF2 Special provisions (ADR) : 602 Limited quantities (ADR) : 500g Excepted quantities (ADR) : E2 Packing instructions (ADR) : P410, IBC04 Mixed packing provisions (ADR) : MP14 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Vehicle for tank carriage : AT Transport category (ADR) : 0 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV23 Hazard identification number (Kemler No.) : 423 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 4W
- Transport by sea
Limited quantities (IMDG) : 500 g Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P410 Special packing provisions (IMDG) : PP31, PP40 IBC packing instructions (IMDG) : IBC04 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-G EmS-No. (Spillage) : S-N Stowage category (IMDG) : D Stowage and handling (IMDG) : H1 Segregation (IMDG) : SG26 MFAG-No : 139
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y475 PCA limited quantity max net quantity (IATA) : 5kg PCA packing instructions (IATA) : 483 PCA max net quantity (IATA) : 15kg CAO packing instructions (IATA) : 490 CAO max net quantity (IATA) : 50kg ERG code (IATA) : 4FW
- Inland waterway transport
Classification code (ADN) : WF2 Special provisions (ADN) : 602 Limited quantities (ADN) : 500 g Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Provisions for handling and stowage of the cargo (ADN) : HA08 Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : WF2 Special provisions (RID) : 602 Limited quantities (RID) : 500g Excepted quantities (RID) : E2 Packing instructions (RID) : P410, IBC04 Mixed packing provisions (RID) : MP14 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Transport category (RID) : 0 Special provisions for carriage – Packages (RID) : W1 Special provisions for carriage - Loading, unloading and handling (RID) : CW23 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 423
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Phosphorus pentasulfide is not on the REACH Candidate List Phosphorus pentasulfide is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, Highly hazardous to water (Classification according to AwSV; ID No. 2233) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen - Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen - Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Flam. Sol. 1 Flammable solids, Category 1 Water-react. 1 Substances and Mixtures which, in contact with water, emit flammable gases, Category 1 H228 Flammable solid. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H332 Harmful if inhaled. H400 Very toxic to aquatic life. R11 Highly flammable R20/22 Harmful by inhalation and if swallowed R29 Contact with water liberates toxic gas R50 Very toxic to aquatic organisms F Highly flammable N Dangerous for the environment Xn Harmful