SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	1-CHLORO-2, 4-DINITROBENZENE (for synthesis)
Catalogue No. :	AL1292	Product form :	Substance
CAS Number :	97-00-7	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	29042090
Synonyms :	2,4-Dinitrochlorobenzene
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 3 H301 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye H318 irritation, Category 1 Specific target organ toxicity Repeated exposure, Category 2 H373 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Muta.Cat.3; R68 T; R23/24/25 N; R50/53 R33 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS06 GHS08 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation. H318 - Causes serious eye damage. H373 - May cause damage to organs through prolonged or repeated exposure. H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P261 - Avoid breathing vapours, dust, fume, gas. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362+P364 - Take off contaminated clothing and wash it before reuse. P311 - Call a doctor.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		1-CHLORO-2,4-DINITROBENZENE For Synthesis
CAS No. :		97-00-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact :	Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
First-aid measures after ingestion :	Rinse mouth. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects : May cause damage to organs through prolonged or repeated exposure. Symptoms/effects after inhalation : Toxic if inhaled. Symptoms/effects after skin contact : Toxic in contact with skin. Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye damage. Symptoms/effects after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	202.55 g/mol
Colour :	Yellow Crystals.
Odour :	almond-like.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	48 - 50 °C
Freezing point :	No data available
Boiling point :	315 °C
Flash point :	186 °C
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	6.98
Density :	1.687 g/cm3
Solubility :	Water: Insoluble
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	0.02 - 0.22 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled.
Skin corrosion/irritation :	Causes skin irritation.
Serious eye damage/irritation :	Causes serious eye damage.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	May cause damage to organs through prolonged or repeated exposure. Additional information : There are potential chronic health effects to consider
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability :	1-CHLORO-2,4-DINITROBENZENE For Synthesis (97-00-7) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3441
UN-No. (IMDG) :	3441
UN-No. (IATA) :	3441
UN-No. (ADN) :	3441
UN-No. (RID) :	3441
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CHLORODINITROBENZENES, SOLID
Proper Shipping Name (IMDG) :	CHLORODINITROBENZENES, SOLID
Proper Shipping Name (IATA) :	CHLORODINITROBENZENES, SOLID
Proper Shipping Name (ADN) :	CHLORODINITROBENZENES, SOLID
Proper Shipping Name (RID) :	CHLORODINITROBENZENES, SOLID
Transport document description (ADR) :	UN 3441, CHLORODINITROBENZENES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 3441, CHLORODINITROBENZENES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 3441, CHLORODINITROBENZENES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 3441, CHLORODINITROBENZENES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 3441, CHLORODINITROBENZENES, SOLID, 6.1, II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1
Danger labels :	6.1
IMDG
Transport hazard class(es) :	6.1
Danger labels :	6.1
IATA
Transport hazard class(es) :	6.1
Danger labels :	6.1
ADN
Transport hazard class(es) :	6.1
Danger labels :	6.1
RID
Transport hazard class(es) :	6.1
Danger labels :	6.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T2 Special provisions (ADR) : 279 Limited quantities (ADR) : 500g Excepted quantities (ADR) : E4 Packing instructions (ADR) : P002, IBC08 Special packing provisions (ADR) : B4 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X
- Transport by sea
Special provisions (IMDG) : 279 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B21, B4 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Segregation (IMDG) : SG15 Properties and observations (IMDG) : Crystals. Melting point: 27°C to 53°C. May explode if involved in a fire. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 153
- Air transport
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y644 PCA limited quantity max net quantity (IATA) : 1kg PCA packing instructions (IATA) : 669 PCA max net quantity (IATA) : 25kg CAO packing instructions (IATA) : 676 CAO max net quantity (IATA) : 100kg Special provisions (IATA) : A113 ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T2 Special provisions (ADN) : 279, 802 Limited quantities (ADN) : 500 g Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : T2 Special provisions (RID) : 279 Excepted quantities (RID) : E4 Packing instructions (RID) : P002, IBC08 Special packing provisions (RID) : B4 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE9 Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions 1-CHLORO-2,4-DINITROBENZENE For Synthesis is not on the REACH Candidate List 1-CHLORO-2,4-DINITROBENZENE For Synthesis is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, significant hazard to water (Classification according to AwSV; ID No. 1120) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H301 Toxic if swallowed. H311 Toxic in contact with skin. H315 Causes skin irritation. H318 Causes serious eye damage. H331 Toxic if inhaled. H373 May cause damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R33 Danger of cumulative effects R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R68 Possible risk of irreversible effects N Dangerous for the environment T Toxic