PYROGALLOL AR |
Synonyms : 1,2,3-trihydroxybenzene |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | PYROGALLOL AR | ||
Catalogue No. : | AL3875 | Product form : | Substance |
CAS Number : | 87-66-1 | EC Number : | 201-762-9 |
Grade : | EC Index Number : | 604-009-00-6 | |
Chemical Formula : | HSN Code : | 29072990 | |
Synonyms : | 1,2,3-trihydroxybenzene | ||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 4 H332 Acute toxicity (oral), Category 4 H302 Germ cell mutagenicity, Category 2 H341 Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of classification categories and H statements : see section 16 |
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Classification according to Directive 67/548/EEC or 1999/45/EC | |
Muta.Cat.3; R68 Xn; R20/21/22 R52/53 Full text of R-phrases: see section 16 |
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Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS08 GHS07 |
Signal word (CLP) : | - |
Hazard statements (CLP) : | H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled H341 - Suspected of causing genetic defects H412 - Harmful to aquatic life with long lasting effects |
Precautionary statements (CLP) : | P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Name : | PYROGALLOL AR | ||
CAS No. : | 87-66-1 | ||
EC Index No. : | 604-009-00-6 | ||
EC No. : | 201-762-9 | ||
Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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Not applicable |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
First-aid measures after skin contact : | Immediately call a POISON CENTER or doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and water. Wash contaminated clothing before reuse. |
First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/injuries : Suspected of causing genetic defects. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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Special procedures : | No additional information available |
5.3 Advice for firefighters |
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Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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Protective equipment | Use personal protective equipment as required |
Emergency procedures | Stop release. |
6.2 Environmental precautions |
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Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Precautions for safe handling : | Obtain special instructions before use. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. |
Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | protective gloves |
Eye protection : | Chemical goggles or safety glasses |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Solid Colour |
Colour : | White powder. |
Odour : | characteristic odor. |
Odour threshold : | No data available |
pH value : | 5.8 at 10 g/l |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | 133 - 134 |
Freezing point : | No data available |
Boiling point : | 309 °C |
Flash point : | No data available |
Auto-ignition temperature : | No data available |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | No data available |
Vapour pressure : | No data available |
Relative vapour density at 20°C : | 4.4 |
Density : | 1.45 g/cm3 |
Solubility : | Water: 60 g/100ml @ 200C |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | No data available |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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No additional information available | |
10.2 Chemical stability |
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Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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No additional information available | |
10.6 Hazardous decomposition products |
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No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled. Oral: Harmful if swallowed. |
Skin corrosion/irritation : | Not classified pH: 5.8 at 10 g/l |
Serious eye damage/irritation : | Not classified pH: 5.8 at 10 g/l |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Suspected of causing genetic defects. |
Carcinogenicity : | Not classified |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | Not classified |
Specific target organ toxicity (repeated exposure) : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | Ecology - water : Harmful to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
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Persistence - degradability : | PYROGALLOL AR (87-66-1) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 2811 |
UN-No. (IMDG) : | 2811 |
UN-No. (IATA) : | 2811 |
UN-No. (ADN) : | 2811 |
UN-No. (RID) : | 2811 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | TOXIC SOLID, ORGANIC, N.O.S. |
Proper Shipping Name (IMDG) : | TOXIC SOLID, ORGANIC, N.O.S. |
Proper Shipping Name (IATA) : | TOXIC SOLID, ORGANIC, N.O.S. |
Proper Shipping Name (ADN) : | TOXIC SOLID, ORGANIC, N.O.S. |
Proper Shipping Name (RID) : | TOXIC SOLID, ORGANIC, N.O.S. |
Transport document description (ADR) : | UN 2811, TOXIC SOLID, ORGANIC, N.O.S., 6.1, III |
Transport document description (IMDG) : | UN 2811, TOXIC SOLID, ORGANIC, N.O.S., 6.1, III |
Transport document description (IATA) : | UN 2811, TOXIC SOLID, ORGANIC, N.O.S., 6.1, III |
Transport document description (ADN) : | UN 2811, TOXIC SOLID, ORGANIC, N.O.S., 6.1, III |
Transport document description (RID) : | UN 2811, TOXIC SOLID, ORGANIC, N.O.S., 6.1, III |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 6.1 |
Danger labels : | 6.1 |
IMDG | |
Transport hazard class(es) : | 6.1 |
Danger labels : | 6.1 |
IATA | |
Transport hazard class(es) : | 6.1 |
Danger labels : | 6.1 |
ADN | |
Transport hazard class(es) : | 6.1 |
Danger labels : | 6.1 |
RID | |
Transport hazard class(es) : | 6.1 |
Danger labels : | 6.1 |
14.4. Packing group |
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Packing group (ADR) : | III |
Packing group (IMDG) : | III |
Packing group (IATA) : | III |
Packing group (ADN) : | III |
Packing group (RID) : | III |
14.5. Environmental hazards |
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Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : T2 Special provision (ADR) : 274, 614 Limited quantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X |
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- Transport by sea | |
Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A MFAG-No : 154 |
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- Air transport | |
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y645 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 670 PCA max net quantity (IATA) : 100kg CAO packing instructions (IATA) : 677 CAO max net quantity (IATA) : 200kg Special provision (IATA) : A3, A5 ERG code (IATA) : 6L |
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- Inland waterway transport | |
Classification code (ADN) : T2 Special provisions (ADN) : 274, 614, 802 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
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- Rail transport | |
Classification code (RID) : T2 Special provision (RID) : 274, 614 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 60 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
No REACH Annex XVII restrictions PYROGALLOL AR is not on the REACH Candidate List PYROGALLOL AR is not on the REACH Annex XIV List |
15.1.2. National regulations |
Germany |
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 3; WGK No 2943) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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