SODIUM HYDRIDE SUSPENSION IN PARAFFIN OIL Extra Pure |
| Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | SODIUM HYDRIDE SUSPENSION | ||
| Catalogue No. : | AL4154 | Product form : | Substance |
| CAS Number : | 7646-69-7 | EC Number : | 231-587-3 |
| Grade : | EC Index Number : | 001-003-00-X | |
| Chemical Formula : | HSN Code : | 28500010 | |
| Synonyms : | |||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Substances and Mixtures which, in contact with water, emit flammable gases, Category 1 H260 Serious eye damage/eye irritation, Category 2 H319 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| F; R15 Xi; R36 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS07
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H260 - In contact with water releases flammable gases which may ignite spontaneously. H319 - Causes serious eye irritation. |
| Precautionary statements (CLP) : | P223 - Do not allow contact with water. P231+P232 - Handle under inert gas. Protect from moisture. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P370+P378 - In case of fire: Use ... to extinguish. P422 - Store contents under inert gas |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | SODIUM HYDRIDE SUSPENSION IN PARAFFIN OIL Extra Pure | ||
| CAS No. : | 7646-69-7 | ||
| EC Index No. : | 001-003-00-X | ||
| EC No. : | 231-587-3 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth out with water. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Dry powder. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | In contact with water releases flammab |
| Explosion hazard : | |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
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| Do not allow contact with water. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Do not allow contact with water. |
| Precautions for safe handling : | Protect from moisture. Handle under inert gas. |
| Hygiene measures : | Wash hands, forearms and face thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a dry place. Protect from moisture. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear fire/flame resistant/retardant clothing. |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 24 g/mol |
| Colour : | Light grey powder. |
| Odour : | odourless. |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 8000 °C |
| Freezing point : | No data available |
| Boiling point : | No data available |
| Flash point : | No data available |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | In contact with water releases flammable gases whi |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 1.2 g/cm3 |
| Solubility : | Water: Insoluble in water |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| Do not allow contact with water. | |
10.2 Chemical stability |
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| No additional information available | |
10.3 Possibility of hazardous reactions |
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| In contact with water releases flammable gases which may ignite spontaneously. | |
10.4 Conditions to avoid |
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| Direct sunlight. Overheating. Open flame. Heat. Sparks. Water, humidity. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Not classified |
| Skin corrosion/irritation : | Not classified |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | Not classified |
| STOT-repeated exposure : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1427 |
| UN-No. (IMDG) : | 1427 |
| UN-No. (IATA) : | 1427 |
| UN-No. (ADN) : | 1427 |
| UN-No. (RID) : | 1427 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | SODIUM HYDRIDE |
| Proper Shipping Name (IMDG) : | SODIUM HYDRIDE |
| Proper Shipping Name (IATA) : | SODIUM HYDRIDE |
| Proper Shipping Name (ADN) : | SODIUM HYDRIDE |
| Proper Shipping Name (RID) : | SODIUM HYDRIDE |
| Transport document description (ADR) : | UN 1427, SODIUM HYDRIDE, 4.3, I |
| Transport document description (IMDG) : | UN 1427, SODIUM HYDRIDE, 4.3, I |
| Transport document description (IATA) : | UN 1427, SODIUM HYDRIDE, 4.3, I |
| Transport document description (ADN) : | UN 1427, SODIUM HYDRIDE, 4.3, I |
| Transport document description (RID) : | UN 1427, SODIUM HYDRIDE, 4.3, I |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3 
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| IMDG | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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| IATA | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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| ADN | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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| RID | |
| Transport hazard class(es) : | 4.3 |
| Danger labels : | 4.3
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14.4. Packing group |
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| Packing group (ADR) : | I |
| Packing group (IMDG) : | I |
| Packing group (IATA) : | I |
| Packing group (ADN) : | I |
| Packing group (RID) : | I |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : W2 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P403 Mixed packing provisions (ADR) : MP2 Transport category (ADR) : 1 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV23 Special provisions for carriage - Operation (ADR) : S20 Tunnel restriction code (ADR) : E EAC code : 4W |
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| - Transport by sea | |
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Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P403 Special packing provisions (IMDG) : PP31 EmS-No. (Fire) : F-G EmS-No. (Spillage) : S-O Stowage category (IMDG) : E Stowage and handling (IMDG) : H1 Segregation (IMDG) : SG35, SG26 MFAG-No : 138 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : 487 CAO max net quantity (IATA) : 15kg ERG code (IATA) : 4W |
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| - Inland waterway transport | |
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Classification code (ADN) : W2 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Provisions for handling and stowage of the cargo (ADN) : HA08 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : W2 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P403 Mixed packing provisions (RID) : MP2 Transport category (RID) : 1 Special provisions for carriage – Packages (RID) : W1 Special provisions for carriage - Loading, unloading and handling (RID) : CW23 Hazard identification number (RID) : X423 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions SODIUM HYDRIDE SUSPENSION IN PARAFFIN OIL Extra Pure is not on the REACH Candidate List SODIUM HYDRIDE SUSPENSION IN PARAFFIN OIL Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen � Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen � Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen � Ontwikkeling : The substance is not listed |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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