1-FLUORO-2,4-DINITROBENZENE AR |
| Synonyms : Sanger's reagent |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | 2,4-DINITRO-1-FLUOROBENZENE AR | ||
| Catalogue No. : | AL1897 | Product form : | Substance |
| CAS Number : | 70-34-8 | EC Number : | |
| Grade : | EC Index Number : | ||
| Chemical Formula : | C6H3FN2O4 | HSN Code : | 29049990 |
| Synonyms : | Sanger's reagent | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Industrial For professional use only | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 4 H302 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Skin sensitisation, Category 1 H317 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Specific target organ toxicity Repeated exposure, Category 2 H373 Full text of H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R22 Xi; R36/37/38 R43 R33 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS07
 GHS08
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| Signal word (CLP) : | Warning |
| Hazard statements (CLP) : | H302 - Harmful if swallowed. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H373 - May cause damage to organs through prolonged or repeated exposure. |
| Precautionary statements (CLP) : | P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P261 - Avoid breathing dust, fume, gas, spray, vapours, mist. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | 1-FLUORO-2,4-DINITROBENZENE AR | ||
| CAS No. : | 70-34-8 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get immediate medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects : There are potential chronic health effects to consider. Symptoms/effects after inhalation : May cause an allergic skin reaction. May cause respiratory irritation. Symptoms/effects after skin contact : Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Water spray. Foam. Dry powder. Carbon dioxide. |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands, forearms and face thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | [In case of inadequate ventilation] wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 186.1 g/mol |
| Colour : | Yellow to red. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 27.5 - 30 °C |
| Freezing point : | No data available |
| Boiling point : | 178 °C |
| Flash point : | 164 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 1.4718 g/cm3 |
| Solubility : | Water: Insoluble |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Extremely high or low temperatures. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| STOT-single exposure : | May cause respiratory irritation. |
| STOT-repeated exposure : | May cause damage to organs through prolonged or repeated exposure. Additional information : There are potential chronic health effects to consider |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | Not applicable |
| UN-No. (IMDG) : | Not applicable |
| UN-No. (IATA) : | Not applicable |
| UN-No. (ADN) : | Not applicable |
| UN-No. (RID) : | Not applicable |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | Not applicable |
| Proper Shipping Name (IMDG) : | Not applicable |
| Proper Shipping Name (IATA) : | Not applicable |
| Proper Shipping Name (ADN) : | Not applicable |
| Proper Shipping Name (RID) : | Not applicable |
| Transport document description (ADR) : | Not applicable |
| Transport document description (IMDG) : | Not applicable |
| Transport document description (IATA) : | Not applicable |
| Transport document description (ADN) : | Not applicable |
| Transport document description (RID) : | Not applicable |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | Not applicable |
| IMDG | |
| Transport hazard class(es) : | Not applicable |
| IATA | |
| Transport hazard class(es) : | Not applicable |
| ADN | |
| Transport hazard class(es) : | Not applicable |
| RID | |
| Transport hazard class(es) : | Not applicable |
14.4. Packing group |
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| Packing group (ADR) : | Not applicable |
| Packing group (IMDG) : | Not applicable |
| Packing group (IATA) : | Not applicable |
| Packing group (ADN) : | Not applicable |
| Packing group (RID) : | Not applicable |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
| No data available | |
| - Transport by sea | |
| No data available | |
| - Air transport | |
| No data available | |
| - Inland waterway transport | |
| No data available | |
| - Rail transport | |
| No data available | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions 1-FLUORO-2,4-DINITROBENZENE AR is not on the REACH Candidate List 1-FLUORO-2,4-DINITROBENZENE AR is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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