SODIUM METHOXIDE 30% SOLUTION IN METHANOL

SODIUM METHOXIDE 30% SOLUTION IN METHANOL

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : SODIUM METHOXIDE 30% Solution (In Methanol)
Catalogue No. : AL4204 Product form : Mixture
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 38220090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS05GHS05 GHS06GHS06 GHS08GHS08
Signal word (CLP) : Danger
Hazard statements (CLP) : H225 - Highly flammable liquid and vapour.
H251 - Self-heating: may catch fire.
H301+H311 - Toxic if swallowed or in contact with skin
H314 - Causes severe skin burns and eye damage.
H370 - Causes damage to organs.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P260 - Do not breathe dust/fume/gas/mist/vapours/spray.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
Methanol (CAS-No.) 67-56-1 (EC-No.) 200-659-6 (EC Index-No.) 603-001-00-X 50 - 75 Flam. Liq. 2, H225 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Oral), H301 STOT SE 1, H370
Sodium methylate (CAS-No.) 124-41-4 (EC-No.) 204-699-5 (EC Index-No.) 603-040-00-2 25 - 50 Self-heat. 1, H251 Skin Corr. 1B, H314
Full text of H-statements: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : If you feel unwell, seek medical advice. Rinse mouth out with water.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage. Causes damage to organs.
Symptoms/effects after skin contact : Toxic in contact with skin.
Symptoms/effects after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Highly flammable liquid and vapour.
Explosion hazard : Heating may cause a fire or explosion.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Avoid contact with skin, eyes and clothing.
6.1.2. For emergency responders
Protective equipment Avoid breathing dust/fume/gas/mist/vapours/spray
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean contaminated surfaces with an excess of water.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear Colorless.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : < 6 °C
Freezing point : No data available
Boiling point : 93 °C
Flash point : 16.5 °C
Auto-ignition temperature : 463.89 °C
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 34 hPa at 20 °C
Relative vapour density at 20°C : No data available
Density : 0.97 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 0.055 - 0.265 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Heat. High temperature. Open flame. Overheating.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed. Dermal: Toxic in contact with skin.
ATE CLP (oral) 100 mg/kg bodyweight
ATE CLP (dermal) 300 mg/kg bodyweight
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye
damage, category 1, implicit
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Causes damage to organs.
STOT-repeated exposure : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Toxic if swallowed. Toxic in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Ecology - waste materials : Hazardous waste due to toxicity.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1289
UN-No. (IMDG) : 1289
UN-No. (IATA) : 1289
UN-No. (ADN) : 1289
UN-No. (RID) : 1289
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM METHYLATE SOLUTION
Proper Shipping Name (IMDG) : SODIUM METHYLATE SOLUTION
Proper Shipping Name (IATA) : SODIUM METHYLATE SOLUTION
Proper Shipping Name (ADN) : SODIUM METHYLATE SOLUTION
Proper Shipping Name (RID) : SODIUM METHYLATE SOLUTION
Transport document description (ADR) : UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II
Transport document description (IMDG) : UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II
Transport document description (IATA) : UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II
Transport document description (ADN) : UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II
Transport document description (RID) : UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
IMDG
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
IATA
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
ADN
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
RID
Transport hazard class(es) : 3 (8)
Danger labels : 3, 8
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FC
Limited quantities (ADR) : 1l
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP1, TP8
Tank code (ADR) : L4BH
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Operation
(ADR)
: S2, S20
Hazard identification number (Kemler No.) : 338
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2WE
APP code : A(fl)
- Transport by sea
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP1, TP8
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-C
Stowage category (IMDG) : B
Properties and observations (IMDG) : Reacts violently with water. Causes burns to skin, eyes and mucous membranes.
MFAG-No : 132
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y340
PCA limited quantity max net quantity
(IATA)
: 0.5L
PCA packing instructions (IATA) : 352
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 363
CAO max net quantity (IATA) : 5L
Special provisions (IATA) : A3, A803
ERG code (IATA) : 3C
- Inland waterway transport
Classification code (ADN) : FC
Limited quantities (ADN) : 1 L
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP, EP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : FC
Limited quantities (RID) : 1L
Excepted quantities (RID) : E2
Packing instructions (RID) : P001, IBC02
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID)
: T7
Portable tank and bulk container special
provisions (RID)
: TP1, TP8
Tank codes for RID tanks (RID) : L4BH
Transport category (RID) : 2
Colis express (express parcels) (RID) : CE7
Hazard identification number (RID) : 338
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions
Contains no substance on the REACH candidate list
Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 2, Significantly hazardous to water (Classification
according to AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : None of the components are listed
SZW-lijst van mutagene stoffen : None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: None of the components are listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: None of the components are listed
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage
of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Flam. Liq. 2 Flammable liquids, Category 2
Self-heat. 1 Self-Heating Substances and Mixtures, Category 1
Skin Corr. 1B Skin corrosion/irritation, Category 1B
STOT SE 1 Specific target organ toxicity — single exposure, Category 1
H225 Highly flammable liquid and vapour.
H251 Self-heating: may catch fire.
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H331 Toxic if inhaled.
H370 Causes damage to organs.