SODIUM METHOXIDE 30% SOLUTION IN METHANOL |
Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | SODIUM METHOXIDE 30% Solution (In Methanol) | ||
Catalogue No. : | AL4204 | Product form : | Mixture |
CAS Number : | EC Number : | ||
Grade : | EC Index Number : | ||
Chemical Formula : | HSN Code : | 38220090 | |
Synonyms : | |||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Industrial For professional use only | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Not classified see section 16 | |
Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS02 GHS05 GHS06 GHS08 |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H225 - Highly flammable liquid and vapour. H251 - Self-heating: may catch fire. H301+H311 - Toxic if swallowed or in contact with skin H314 - Causes severe skin burns and eye damage. H370 - Causes damage to organs. |
Precautionary statements (CLP) : | P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Not applicable | |||
3.2. Mixture |
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Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
Methanol | (CAS-No.) 67-56-1 (EC-No.) 200-659-6 (EC Index-No.) 603-001-00-X | 50 - 75 | Flam. Liq. 2, H225 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Oral), H301 STOT SE 1, H370 |
Sodium methylate | (CAS-No.) 124-41-4 (EC-No.) 204-699-5 (EC Index-No.) 603-040-00-2 | 25 - 50 | Self-heat. 1, H251 Skin Corr. 1B, H314 |
Full text of H-statements: see section 16 |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. |
First-aid measures after skin contact : | Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. |
First-aid measures after ingestion : | If you feel unwell, seek medical advice. Rinse mouth out with water. |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/effects : Causes severe skin burns and eye damage. Causes damage to organs. Symptoms/effects after skin contact : Toxic in contact with skin. Symptoms/effects after ingestion : Toxic if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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Fire hazard : | Highly flammable liquid and vapour. |
Explosion hazard : | Heating may cause a fire or explosion. |
5.3 Advice for firefighters |
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Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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Emergency procedures : | Avoid contact with skin, eyes and clothing. |
6.1.2. For emergency responders |
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Protective equipment | Avoid breathing dust/fume/gas/mist/vapours/spray |
6.2 Environmental precautions |
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Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | Clean contaminated surfaces with an excess of water. |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Precautions for safe handling : | Avoid contact with skin and eyes. |
Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | Protective gloves |
Eye protection : | Chemical goggles or face shield |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Liquid Colour |
Colour : | Clear Colorless. |
Odour : | No data available |
Odour threshold : | No data available |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | < 6 °C |
Freezing point : | No data available |
Boiling point : | 93 °C |
Flash point : | 16.5 °C |
Auto-ignition temperature : | 463.89 °C |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | No data available |
Vapour pressure : | 34 hPa at 20 °C |
Relative vapour density at 20°C : | No data available |
Density : | 0.97 g/cm3 |
Solubility : | Water: Soluble in water |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | 0.055 - 0.265 vol % |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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No additional information available | |
10.2 Chemical stability |
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Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Direct sunlight. Heat. High temperature. Open flame. Overheating. | |
10.5 Incompatible materials |
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No additional information available | |
10.6 Hazardous decomposition products |
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No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Oral: Toxic if swallowed. Dermal: Toxic in contact with skin. ATE CLP (oral) 100 mg/kg bodyweight ATE CLP (dermal) 300 mg/kg bodyweight |
Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Not classified |
STOT-single exposure : | Causes damage to organs. |
STOT-repeated exposure : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 1289 |
UN-No. (IMDG) : | 1289 |
UN-No. (IATA) : | 1289 |
UN-No. (ADN) : | 1289 |
UN-No. (RID) : | 1289 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | SODIUM METHYLATE SOLUTION |
Proper Shipping Name (IMDG) : | SODIUM METHYLATE SOLUTION |
Proper Shipping Name (IATA) : | SODIUM METHYLATE SOLUTION |
Proper Shipping Name (ADN) : | SODIUM METHYLATE SOLUTION |
Proper Shipping Name (RID) : | SODIUM METHYLATE SOLUTION |
Transport document description (ADR) : | UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II |
Transport document description (IMDG) : | UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II |
Transport document description (IATA) : | UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II |
Transport document description (ADN) : | UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II |
Transport document description (RID) : | UN 1289, SODIUM METHYLATE SOLUTION, 3 (8), II |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 3 (8) |
Danger labels : | 3, 8 |
IMDG | |
Transport hazard class(es) : | 3 (8) |
Danger labels : | 3, 8 |
IATA | |
Transport hazard class(es) : | 3 (8) |
Danger labels : | 3, 8 |
ADN | |
Transport hazard class(es) : | 3 (8) |
Danger labels : | 3, 8 |
RID | |
Transport hazard class(es) : | 3 (8) |
Danger labels : | 3, 8 |
14.4. Packing group |
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Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
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Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : FC Limited quantities (ADR) : 1l Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1, TP8 Tank code (ADR) : L4BH Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Operation (ADR) : S2, S20 Hazard identification number (Kemler No.) : 338 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2WE APP code : A(fl) |
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- Transport by sea | |
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP8 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-C Stowage category (IMDG) : B Properties and observations (IMDG) : Reacts violently with water. Causes burns to skin, eyes and mucous membranes. MFAG-No : 132 |
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- Air transport | |
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y340 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 352 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 363 CAO max net quantity (IATA) : 5L Special provisions (IATA) : A3, A803 ERG code (IATA) : 3C |
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- Inland waterway transport | |
Classification code (ADN) : FC Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 1 |
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- Rail transport | |
Classification code (RID) : FC Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1, TP8 Tank codes for RID tanks (RID) : L4BH Transport category (RID) : 2 Colis express (express parcels) (RID) : CE7 Hazard identification number (RID) : 338 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances |
15.1.2. National regulations |
Germany |
Reference to AwSV : Water hazard class (WGK) 2, Significantly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Netherlands |
SZW-lijst van kankerverwekkende stoffen : None of the components are listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : None of the components are listed |
Denmark |
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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