NITROBENZENE For Synthesis |
| Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
|---|---|---|---|
1.1 Product identifier |
|||
| Chemical Name : | NITROBENZENE | ||
| Catalogue No. : | AL3278 | Product form : | Substance |
| CAS Number : | 98-95-3 | EC Number : | 202-716-0 |
| Grade : | EC Index Number : | 609-003-00-7 | |
| Chemical Formula : | HSN Code : | 29042010 | |
| Synonyms : | |||
| Chemical Structure : |
|
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
||
SECTION 2: Hazards identification |
|
|---|---|
2.1 Classification of the substance or mixture |
|
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
|
Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Specific target organ toxicity Repeated exposure, Category 1 H372 Carcinogenicity, Category 2 H351 Reproductive toxicity, Category 2 H361f Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16 |
|
| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Carc.Cat.3; R40 Repr.Cat.3; R62 T; R23/24/25 T; R48/23/24 N; R51/53 Full text of R-phrases: see section 16 |
|
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
|
| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS06
 GHS08
 GHS09
|
| Signal word (CLP) : | - |
| Hazard statements (CLP) : | H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H351 - Suspected of causing cancer H361f - Suspected of damaging fertility H372 - Causes damage to organs through prolonged or repeated exposure H411 - Toxic to aquatic life with long lasting effects |
| Precautionary statements (CLP) : | P201 - Obtain special instructions before use P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P311 - Call a POISON CENTER or doctor/physician |
2.3 Other hazards |
|
| Other hazards : | This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
SECTION 3: Composition/information on ingredients |
|||
|---|---|---|---|
3.1. Substance |
|||
| Name : | NITROBENZENE FOR SYNTHESIS | ||
| CAS No. : | 98-95-3 | ||
| EC Index No. : | 609-003-00-7 | ||
| EC No. : | 202-716-0 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
|||
| Not applicable | |||
SECTION 4: First aid measures |
|
|---|---|
4.1 Description of first aid measures |
|
| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | If you feel unwell, seek medical advice. Rinse mouth out with water. |
4.2 Most important symptoms and effects, both acute and delayed |
|
| Symptoms relating to use : | Symptoms/injuries : Suspected of damaging fertility. Causes damage to organs through prolonged or repeated exposure. Symptoms/injuries after inhalation : Toxic if inhaled. Symptoms/injuries after skin contact : Toxic in contact with skin. Symptoms/injuries after ingestion : Harmful if swallowed. Chronic symptoms : Suspected carcinogen. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
|---|---|
5.1 Extinguishing media |
|
| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
| Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
|
|---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. |
6.2 Environmental precautions |
|
| Toxic to aquatic life with long lasting effects. | |
6.3 Methods and material for containment and cleaning up |
|
| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
|
| Reference : | No additional information available |
SECTION 7: Handling and storage |
|
|---|---|
7.1 Precautions for safe handling |
|
| Precautions for safe handling : | Do not get in eyes, on skin, or on clothing. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. |
7.2 Conditions for safe storage, including any incompatibilities |
|
| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
| No additional information available | |
SECTION 8: Exposure controls/personal protection |
|
|---|---|
8.1 Control parameters |
|
| No additional information available | |
8.2 Exposure controls |
|
| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
|---|---|
9.1 Information on basic physical and chemical properties |
|
| Physical state : | Liquid Colour |
| Colour : | Pale yellow. |
| Odour : | almond odor. |
| Odour threshold : | No data available |
| pH value : | 8 - 8.5 at 1,00000 g/l at 20°C |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 5 - 6 |
| Freezing point : | No data available |
| Boiling point : | 210 - 211 |
| Flash point : | 88 °C |
| Auto-ignition temperature : | 482 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 0.3 hPa at 20°C |
| Relative vapour density at 20°C : | 4.3 |
| Density : | 1.2 g/cm3 |
| Solubility : | Water: Practically insoluble in water |
| Log Pow : | 1.85 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | 0.018 - 0.4 vol % |
9.2 Other information |
|
| No additional information available | |
SECTION 10: Stability and reactivity |
|
|---|---|
10.1 Reactivity |
|
| No additional information available | |
10.2 Chemical stability |
|
| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
| No additional information available | |
10.4 Conditions to avoid |
|
| Direct sunlight. Open flame. Overheating. Heat. Sparks. | |
10.5 Incompatible materials |
|
| No additional information available | |
10.6 Hazardous decomposition products |
|
| No additional information available |
SECTION 11: Toxicological information |
|
|---|---|
11.1 Information on toxicological effects |
|
| Acute toxicity : | Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. |
| Skin corrosion/irritation : | Not classified pH: 8 - 8.5 at 1,00000 g/l at 20 °C |
| Serious eye damage/irritation : | Not classified pH: 8 - 8.5 at 1,00000 g/l at 20°C |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| Reproductive toxicity : | Suspected of damaging fertility. |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Causes damage to organs through prolonged or repeated exposure. |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Toxic if swallowed. Toxic in contact with skin. |
SECTION 12: Ecological information |
|
|---|---|
12.1 Toxicity |
|
| Toxicity information : | Ecology - water : Toxic to aquatic life with long lasting effects. |
12.2 Persistence - degradability |
|
| Persistence - degradability : | NITROBENZENE FOR SYNTHESIS (98-95-3) Persistence and degradability May cause long-term adverse effects in the environment. |
12.3 Bioaccumulative potential |
|
| Bioaccumulative potential : | NITROBENZENE FOR SYNTHESIS (98-95-3) Log Pow 1.85 |
12.4 Mobility in soil |
|
| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
| NITROBENZENE FOR SYNTHESIS (98-95-3) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII |
|
12.6 Other adverse effects |
|
| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
|---|---|
13.1 Waste treatment methods |
|
| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
| Ecology - waste materials : | Hazardous waste due to toxicity. |
SECTION 14: Transport information |
|
|---|---|
| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
| UN-No. (ADR) : | 1662 |
| UN-No. (IMDG) : | 1662 |
| UN-No. (IATA) : | 1662 |
| UN-No. (ADN) : | 1662 |
| UN-No. (RID) : | 1662 |
14.2. UN proper shipping name |
|
| Proper Shipping Name (ADR) : | NITROBENZENE |
| Proper Shipping Name (IMDG) : | NITROBENZENE |
| Proper Shipping Name (IATA) : | NITROBENZENE |
| Proper Shipping Name (ADN) : | NITROBENZENE |
| Proper Shipping Name (RID) : | NITROBENZENE |
| Transport document description (ADR) : | UN 1662, NITROBENZENE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 1662, NITROBENZENE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 1662, NITROBENZENE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 1662, NITROBENZENE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 1662, NITROBENZENE, 6.1, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
|
| ADR | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1 
|
| IMDG | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| IATA | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| ADN | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
| RID | |
| Transport hazard class(es) : | 6.1 |
| Danger labels : | 6.1
|
14.4. Packing group |
|
| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
|
| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
|
| - Overland transport | |
|
Classification code (ADR) : T1 Special provision (ADR) : 279 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : 2X |
|
| - Transport by sea | |
|
Special provision (IMDG) : 279 Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 MFAG-No : 152 |
|
| - Air transport | |
|
PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L Special provision (IATA) : A113 ERG code (IATA) : 6L |
|
| - Inland waterway transport | |
|
Classification code (ADN) : T1 Special provisions (ADN) : 279, 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2 |
|
| - Rail transport | |
|
Classification code (RID) : T1 Special provision (RID) : 279 Limited quantities (RID) : 100ml Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 60 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
| Not applicable | |
SECTION 15: Regulatory information |
|---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions Nitrobenzene is on the REACH Candidate List NITROBENZENE FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (KBwS-Beschluss; WGK No 163) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Class for fire hazard : Class III-1 Store unit : 50 liter Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
||||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
||||||||||||||||||||||||