VANILLIN For Synthesis |
| Synonyms : 4-Hydroxy-3-methoxybenzaldehyde |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | VANILINE (for synthesis) | ||
| Catalogue No. : | AL4763 | Product form : | Substance |
| CAS Number : | 121-33-5 | EC Number : | 204-465-2 |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 29124100 | |
| Synonyms : | 4-Hydroxy-3-methoxybenzaldehyde | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (oral), Category 4 H302 Serious eye damage/eye irritation, Category 2 H319 Sensitisation Skin, category 1 H317 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Muta.Cat.3; R68 Repr.Cat.3; R62 Xn; R22 Xi; R36 R43 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS07
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| Signal word (CLP) : | Warning |
| Hazard statements (CLP) : | H302 - Harmful if swallowed H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation |
| Precautionary statements (CLP) : | P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | VANILLIN FOR SYNTHESIS | ||
| CAS No. : | 121-33-5 | ||
| EC No. : | 204-465-2 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove victim to fresh air and keep at rest in a position comfortable for breathing. |
| First-aid measures after skin contact : | Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see ... on this label). Wash contaminated clothing before reuse. Gently wash with plenty of soap and water. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Avoid breathing dust/fume/gas/mist/vapours/spray |
6.2 Environmental precautions |
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| Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Clear up rapidly by scoop or vacuum. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid breathing dust/fume/gas/mist/vapours/spray. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear fire/flame resistant/retardant clothing |
| Respiratory protection : | Wear respiratory protection Other information : Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Solid |
| Molecular mass : | 152.15 g/mol |
| Colour : | White to light yellow. |
| Odour : | aromatic vanilla odour. |
| Odour threshold : | No data available |
| pH value : | 4.3 (10 g/l) |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 81 - 83 |
| Freezing point : | No data available |
| Boiling point : | 170 °C |
| Flash point : | 147 °C |
| Auto-ignition temperature : | 400 °C |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | 1 mm Hg at 107 °C |
| Relative vapour density at 20°C : | 5.2 |
| Density : | 1.056 g/cm3 |
| Solubility : | Water: 11 g/l @ 25°C |
| Log Pow : | 1.4 |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Air contact. Moisture. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. |
| Skin corrosion/irritation : | Not classified pH: 4.3 (10 g/l) |
| Serious eye damage/irritation : | Causes serious eye irritation. pH: 4.3 (10 g/l) |
| Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | VANILLIN FOR SYNTHESIS (121-33-5) Log Pow 1.4 |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | Not applicable |
| UN-No. (IMDG) : | Not applicable |
| UN-No. (IATA) : | Not applicable |
| UN-No. (ADN) : | Not applicable |
| UN-No. (RID) : | Not applicable |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | Not applicable |
| Proper Shipping Name (IMDG) : | Not applicable |
| Proper Shipping Name (IATA) : | Not applicable |
| Proper Shipping Name (ADN) : | Not applicable |
| Proper Shipping Name (RID) : | Not applicable |
| Transport document description (ADR) : | Not applicable |
| Transport document description (IMDG) : | Not applicable |
| Transport document description (IATA) : | Not applicable |
| Transport document description (ADN) : | Not applicable |
| Transport document description (RID) : | Not applicable |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | Not applicable |
| IMDG | |
| Transport hazard class(es) : | Not applicable |
| IATA | |
| Transport hazard class(es) : | Not applicable |
| ADN | |
| Transport hazard class(es) : | Not applicable |
| RID | |
| Transport hazard class(es) : | Not applicable |
14.4. Packing group |
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| Packing group (ADR) : | Not applicable |
| Packing group (IMDG) : | Not applicable |
| Packing group (IATA) : | Not applicable |
| Packing group (ADN) : | Not applicable |
| Packing group (RID) : | Not applicable |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
| No data available | |
| - Transport by sea | |
| No data available | |
| - Air transport | |
| No data available | |
| - Inland waterway transport | |
| No data available | |
| - Rail transport | |
| No data available | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions VANILLIN FOR SYNTHESIS is not on the REACH Candidate List VANILLIN FOR SYNTHESIS is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 2855) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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