![TERT-BUTYL HYDROPEROXIDE 70% IN WATER Extra Pure, Laboratory Chemicals Manufacturer Alpha Chemika TERT-BUTYL HYDROPEROXIDE 70% IN WATER Extra Pure](https://www.alphachemika.co/assets/images/alphamsds-header.png)
TERT-BUTYL HYDROPEROXIDE 70% IN WATER Extra Pure |
Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
---|---|---|---|
1.1 Product identifier |
|||
Chemical Name : | tert-BUTYLHYDROPEROXIDE 70% In Water | ||
Catalogue No. : | AL0981 | Product form : | Mixture |
CAS Number : | EC Number : | ||
Grade : | EC Index Number : | ||
Chemical Formula : | HSN Code : | 29072990 | |
Synonyms : | |||
Chemical Structure : |
![]() |
||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
|
---|---|
2.1 Classification of the substance or mixture |
|
Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Flammable liquids, Category 3 H226 Self-Reactive Substances and Mixtures, Type C H242 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Skin corrosion/irritation, Category 1 H314 Sensitisation Skin, category 1 H317 Germ cell mutagenicity, Category 2 H341 Hazardous to the aquatic environment Chronic Hazard, Category 2 H411 Full text of classification categories and H statements : see section 16 |
|
Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
|
Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : |
![]() ![]() ![]() ![]() ![]() |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H226 - Flammable liquid and vapour H242 - Heating may cause a fire H302 - Harmful if swallowed H311+H331 - Toxic in contact with skin or if inhaled H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H341 - Suspected of causing genetic defects H411 - Toxic to aquatic life with long lasting effects |
Precautionary statements (CLP) : | P220 - Keep/Store away from clothing/¦/combustible materials P261 - Avoid breathing vapours, dust, fume, gas P273 - Avoid release to the environment P280 - Wear protective gloves, protective clothing, eye protection, face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician |
2.3 Other hazards |
|
Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
---|---|---|---|
3.1. Substance |
|||
Not applicable | |||
3.2. Mixture |
|||
Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
tert-Butyl hydroperoxide solution | (CAS No) 75-91-2 | 70 | Acute Tox. 3 (Inhalation), H331 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Oral), H302 |
Water | (CAS No) 7732-18-5 (EC no) 231-791-2 | 25 - 35 | Not classified |
Full text of H-phrases: see section 16 |
SECTION 4: First aid measures |
|
---|---|
4.1 Description of first aid measures |
|
First-aid measures after inhalation : | Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. |
First-aid measures after skin contact : | Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
|
Symptoms relating to use : | Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
---|---|
5.1 Extinguishing media |
|
Suitable extinguishing media : | Carbon dioxide. Dry powder. Water spray. Foam. |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
|
Fire hazard : | Flammable liquid and vapour. |
Explosion hazard : | Heating may cause a fire or explosion. |
5.3 Advice for firefighters |
|
Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
|
---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
Protective equipment | Use personal protective equipment as required |
Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
Toxic to aquatic life with long lasting effects. | |
6.3 Methods and material for containment and cleaning up |
|
Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. |
6.4 Reference to other sections |
|
Reference : | No additional information available |
SECTION 7: Handling and storage |
|
---|---|
7.1 Precautions for safe handling |
|
Precautions for safe handling : | Avoid contact with skin and eyes. Do not breathe vapours. |
Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
|
Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
No additional information available |
SECTION 8: Exposure controls/personal protection |
|
---|---|
8.1 Control parameters |
|
No additional information available | |
8.2 Exposure controls |
|
Hand protection : | Protective gloves |
Eye protection : | Chemical goggles or safety glasses |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
---|---|
9.1 Information on basic physical and chemical properties |
|
Physical state : | Liquid Colour |
Colour : | Colourless. |
Odour : | No data available |
Odour threshold : | No data available |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | No data available |
Freezing point : | No data available |
Boiling point : | No data available |
Flash point : | No data available |
Auto-ignition temperature : | No data available |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | No data available |
Vapour pressure : | No data available |
Relative vapour density at 20°C : | No data available |
Solubility : | No data available |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | No data available |
9.2 Other information |
|
No additional information available |
SECTION 10: Stability and reactivity |
|
---|---|
10.1 Reactivity |
|
No additional information available | |
10.2 Chemical stability |
|
Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
|
No additional information available | |
10.4 Conditions to avoid |
|
Direct sunlight. Overheating. Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
|
No additional information available | |
10.6 Hazardous decomposition products |
|
No additional information available |
SECTION 11: Toxicological information |
|
---|---|
11.1 Information on toxicological effects |
|
Acute toxicity : | Oral: Harmful if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. ATE CLP (oral) 500 mg/kg bodyweight ATE CLP (dermal) 300 mg/kg bodyweight ATE CLP (gases) 700 ppmv/4h ATE CLP (vapours) 3 mg/l/4h ATE CLP (dust,mist) 0.5 mg/l/4h |
Skin corrosion/irritation : | Causes severe skin burns and eye damage. |
Serious eye damage/irritation : | Serious eye damage, category 1, implicit |
Respiratory or skin sensitisation : | May cause an allergic skin reaction. |
Germ cell mutagenicity : | Suspected of causing genetic defects. |
Carcinogenicity : | Not classified |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | Not classified |
Specific target organ toxicity (repeated exposure) : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
|
---|---|
12.1 Toxicity |
|
Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
No additional information available | |
12.6 Other adverse effects |
|
Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
---|---|
13.1 Waste treatment methods |
|
Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
|
---|---|
In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
UN-No. (ADR) : | 3109 |
UN-No. (IMDG) : | 3109 |
UN-No. (IATA) : | 3109 |
UN-No. (ADN) : | 3109 |
UN-No. (RID) : | 3109 |
14.2. UN proper shipping name |
|
Proper Shipping Name (ADR) : | ORGANIC PEROXIDE TYPE F, LIQUID |
Proper Shipping Name (IMDG) : | ORGANIC PEROXIDE TYPE F, LIQUID |
Proper Shipping Name (IATA) : | ORGANIC PEROXIDE TYPE F, LIQUID |
Proper Shipping Name (ADN) : | ORGANIC PEROXIDE TYPE F, LIQUID |
Proper Shipping Name (RID) : | ORGANIC PEROXIDE TYPE F, LIQUID |
Transport document description (ADR) : | UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS |
Transport document description (IMDG) : | UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS |
Transport document description (IATA) : | UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS |
Transport document description (ADN) : | UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS |
Transport document description (RID) : | UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
|
ADR | |
Transport hazard class(es) : | 5.2 |
Danger labels : | 5.2 ![]() ![]() |
IMDG | |
Transport hazard class(es) : | 5.2 |
Danger labels : | 5.2 ![]() ![]() |
IATA | |
Transport hazard class(es) : | 5.2 |
Danger labels : | 5.2 ![]() ![]() |
ADN | |
Transport hazard class(es) : | 5.2 |
Danger labels : | 5.2 ![]() ![]() |
RID | |
Transport hazard class(es) : | 5.2 |
Danger labels : | 5.2 ![]() ![]() |
14.4. Packing group |
|
Packing group (ADR) : | Not applicable |
Packing group (IMDG) : | Not applicable |
Packing group (IATA) : | Not applicable |
Packing group (ADN) : | Not applicable |
Packing group (RID) : | Not applicable |
14.5. Environmental hazards |
|
Dangerous for the environment : | Yes |
Marine pollutant : | Yes |
Other information : | No supplementary information available |
14.6. Special precautions for user |
|
- Overland transport | |
Classification code (ADR) : P1 Special provision (ADR) : 122, 274 Limited quantities (ADR) : 125ml Excepted quantities (ADR) : E0 Packing instructions (ADR) : P520, IBC520 Mixed packing provisions (ADR) : MP4 Portable tank and bulk container instructions (ADR) : T23 Tank code (ADR) : L4BN(+) Tank special provisions (ADR) : TU3, TU13, TU30, TE12, TA2, TM4 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV15, CV22, CV24 Hazard identification number (Kemler No.) : 539 Orange plates : Tunnel restriction code (ADR) : D EAC code : 2W |
|
- Transport by sea | |
Special provision (IMDG) : 122, 274 Limited quantities (IMDG) : 125 ml Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P520 IBC packing instructions (IMDG) : IBC520 Tank instructions (IMDG) : T23 EmS-No. (Fire) : F-J EmS-No. (Spillage) : S-R Stowage category (IMDG) : D Stowage and handling (IMDG) : SW1 Segregation (IMDG) : SG35, SG36, SG72 |
|
- Air transport | |
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : 570 PCA max net quantity (IATA) : 10L CAO packing instructions (IATA) : 570 CAO max net quantity (IATA) : 25L Special provision (IATA) : A20, A150 ERG code (IATA) : 5L |
|
- Inland waterway transport | |
Classification code (ADN) : P1 Special provisions (ADN) : 122, 274 Limited quantities (ADN) : 125 ml Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 0 |
|
- Rail transport | |
Classification code (RID) : P1 Special provision (RID) : 122, 274 Limited quantities (RID) : 125ml Excepted quantities (RID) : E0 Packing instructions (RID) : P520, IBC520 Mixed packing provisions (RID) : MP4 Portable tank and bulk container instructions (RID) : T23 Tank codes for RID tanks (RID) : L4BN(+) Special provisions for RID tanks (RID) : TU3, TU13, TU30, TE12, TA2, TM4 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W7 Special provisions for carriage – Loading and unloading (RID) : CW22, CW24, CW29 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 539 |
|
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
Not applicable |
SECTION 15: Regulatory information |
---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances. |
15.1.2. National regulations |
Germany |
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|