TERT-BUTYL HYDROPEROXIDE 70% IN WATER Extra Pure

TERT-BUTYL HYDROPEROXIDE 70% IN WATER Extra Pure

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : tert-BUTYLHYDROPEROXIDE 70% In Water
Catalogue No. : AL0981 Product form : Mixture
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 29072990
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Flammable liquids,
Category 3
H226
Self-Reactive Substances
and Mixtures, Type C
H242
Acute toxicity (oral),
Category 4
H302
Acute toxicity (dermal),
Category 3
H311
Acute toxicity (inhal.),
Category 3
H331
Skin corrosion/irritation,
Category 1
H314
Sensitisation Skin,
category 1
H317
Germ cell mutagenicity,
Category 2
H341
Hazardous to the aquatic
environment Chronic
Hazard, Category 2
H411
Full text of classification categories and H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS05GHS05 GHS06GHS06 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H226 - Flammable liquid and vapour
H242 - Heating may cause a fire
H302 - Harmful if swallowed
H311+H331 - Toxic in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
H317 - May cause an allergic skin reaction
H341 - Suspected of causing genetic defects
H411 - Toxic to aquatic life with long lasting effects
Precautionary statements (CLP) : P220 - Keep/Store away from clothing/¦/combustible materials
P261 - Avoid breathing vapours, dust, fume, gas
P273 - Avoid release to the environment
P280 - Wear protective gloves, protective clothing, eye protection, face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
tert-Butyl hydroperoxide solution (CAS No) 75-91-2 70 Acute Tox. 3 (Inhalation), H331 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Oral), H302
Water (CAS No) 7732-18-5 (EC no) 231-791-2 25 - 35 Not classified
Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep
at rest in a position comfortable for breathing.
First-aid measures after skin contact : Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap
and water. Wash contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing
significant health hazard. Harmful in contact with skin.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Water spray. Foam.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : Heating may cause a fire or explosion.
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Colourless.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Oral: Harmful if swallowed. Dermal: Toxic in contact with skin. Inhalation: Toxic if
inhaled.
ATE CLP (oral) 500 mg/kg bodyweight
ATE CLP (dermal) 300 mg/kg bodyweight
ATE CLP (gases) 700 ppmv/4h
ATE CLP (vapours) 3 mg/l/4h
ATE CLP (dust,mist) 0.5 mg/l/4h
Skin corrosion/irritation : Causes severe skin burns and eye damage.
Serious eye damage/irritation : Serious eye damage, category 1, implicit
Respiratory or skin sensitisation : May cause an allergic skin reaction.
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3109
UN-No. (IMDG) : 3109
UN-No. (IATA) : 3109
UN-No. (ADN) : 3109
UN-No. (RID) : 3109
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ORGANIC PEROXIDE TYPE F, LIQUID
Proper Shipping Name (IMDG) : ORGANIC PEROXIDE TYPE F, LIQUID
Proper Shipping Name (IATA) : ORGANIC PEROXIDE TYPE F, LIQUID
Proper Shipping Name (ADN) : ORGANIC PEROXIDE TYPE F, LIQUID
Proper Shipping Name (RID) : ORGANIC PEROXIDE TYPE F, LIQUID
Transport document description (ADR) : UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 3109, ORGANIC PEROXIDE TYPE F, LIQUID, 5.2, Not applicable ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.2
Danger labels : 5.2
IMDG
Transport hazard class(es) : 5.2
Danger labels : 5.2
IATA
Transport hazard class(es) : 5.2
Danger labels : 5.2
ADN
Transport hazard class(es) : 5.2
Danger labels : 5.2
RID
Transport hazard class(es) : 5.2
Danger labels : 5.2
14.4. Packing group
Packing group (ADR) : Not applicable
Packing group (IMDG) : Not applicable
Packing group (IATA) : Not applicable
Packing group (ADN) : Not applicable
Packing group (RID) : Not applicable
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : P1
Special provision (ADR) : 122, 274
Limited quantities (ADR) : 125ml
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P520, IBC520
Mixed packing provisions (ADR) : MP4
Portable tank and bulk container
instructions (ADR)
: T23
Tank code (ADR) : L4BN(+)
Tank special provisions (ADR) : TU3, TU13, TU30, TE12, TA2, TM4
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR)
: V1
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV15, CV22, CV24
Hazard identification number (Kemler No.) : 539
Orange plates :
Tunnel restriction code (ADR) : D
EAC code : 2W
- Transport by sea
Special provision (IMDG) : 122, 274
Limited quantities (IMDG) : 125 ml
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P520
IBC packing instructions (IMDG) : IBC520
Tank instructions (IMDG) : T23
EmS-No. (Fire) : F-J
EmS-No. (Spillage) : S-R
Stowage category (IMDG) : D
Stowage and handling (IMDG) : SW1
Segregation (IMDG) : SG35, SG36, SG72
- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : 570
PCA max net quantity (IATA) : 10L
CAO packing instructions (IATA) : 570
CAO max net quantity (IATA) : 25L
Special provision (IATA) : A20, A150
ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : P1
Special provisions (ADN) : 122, 274
Limited quantities (ADN) : 125 ml
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : P1
Special provision (RID) : 122, 274
Limited quantities (RID) : 125ml
Excepted quantities (RID) : E0
Packing instructions (RID) : P520, IBC520
Mixed packing provisions (RID) : MP4
Portable tank and bulk container
instructions (RID)
: T23
Tank codes for RID tanks (RID) : L4BN(+)
Special provisions for RID tanks (RID) : TU3, TU13, TU30, TE12, TA2, TM4
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID)
: W7
Special provisions for carriage – Loading
and unloading (RID)
: CW22, CW24, CW29
Colis express (express parcels) (RID) : CE6
Hazard identification number (RID) : 539
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-phrases:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 2 Hazardous to the aquatic environment — Chronic Hazard, Category 2
Flam. Liq. 3 Flammable liquids, Category 3
Muta. 2 Germ cell mutagenicity, Category 2
Self-react. C Self-Reactive Substances and Mixtures, Type C
Skin Corr. 1 Skin corrosion/irritation, Category 1
Skin Sens. 1 Sensitisation — Skin, category 1
H226 Flammable liquid and vapour
H242 Heating may cause a fire
H302 Harmful if swallowed
H311 Toxic in contact with skin
H312 Harmful in contact with skin
H314 Causes severe skin burns and eye damage
H317 May cause an allergic skin reaction
H331 Toxic if inhaled
H341 Suspected of causing genetic defects
H411 Toxic to aquatic life with long lasting effects