SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	SULPHUR MONOCHLORIDE (for synthesis)
Catalogue No. :	AL4427	Product form :	Substance
CAS Number :	10025-67-9	EC Number :	233-036-2
Grade :		EC Index Number :
Chemical Formula :	S2Cl2	HSN Code :	28129000
Synonyms :	Sulfur chloride
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (oral), Category 3 H301 Acute toxicity (inhal.), Category 4 H332 Skin corrosion/irritation, Category 1A H314 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
T; R25 Xn; R20 C; R35 N; R50 R14 R29 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS05 GHS06 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H301 - Toxic if swallowed H314 - Causes severe skin burns and eye damage H332 - Harmful if inhaled H400 - Very toxic to aquatic life
Precautionary statements (CLP) :	P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		SULPHUR MONOCHLORIDE FOR SYNTHESIS
CAS No. :		10025-67-9
EC No. :		233-036-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Take off contaminated clothing. Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. Do not induce vomiting because of corrosive effects. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : Harmful if inhaled. Symptoms/injuries after ingestion : Toxic if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release. Ventilate area.
6.2 Environmental precautions
Avoid release to the environment. Do not allow water (or moist air) contact with this material.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations.
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Yellowish red.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	-80 °C
Freezing point :	No data available
Boiling point :	138 °C
Flash point :	No data available
Auto-ignition temperature :	233 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	9.1 hPa at 20 °C
Relative vapour density at 20°C :	4.66
Density :	1.688 g/cm3
Solubility :	No data available
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours. Reacts violently with water.
10.2 Chemical stability
No additional information available
10.3 Possibility of hazardous reactions
Highly reactive material. Reacts violently with water. Contact with water liberates toxic gas.
10.4 Conditions to avoid
Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Toxic if swallowed. Inhalation: Harmful if inhaled.
Skin corrosion/irritation :	Causes severe skin burns and eye damage.
Serious eye damage/irritation :	Serious eye damage, category 1, implicit
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Toxic if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Do not allow water (or moist air) contact with this material.
Ecology - waste materials :	Hazardous waste due to toxicity.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3390
UN-No. (IMDG) :	3390
UN-No. (IATA) :	3390
UN-No. (ADN) :	3390
UN-No. (RID) :	3390
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
Proper Shipping Name (IMDG) :	TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
Proper Shipping Name (IATA) :	TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
Proper Shipping Name (ADN) :	TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
Proper Shipping Name (RID) :	TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S.
Transport document description (ADR) :	UN 3390, TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S., 6.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 3390, TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S., 6.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 3390, TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S., 6.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 3390, TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S., 6.1 (8), I ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 3390, TOXIC BY INHALATION LIQUID, CORROSIVE, N.O.S., 6.1 (8), I ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
IMDG
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
IATA
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
ADN
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
RID
Transport hazard class(es) :	6.1 (8)
Danger labels :	6.1, 8
14.4. Packing group
Packing group (ADR) :	I
Packing group (IMDG) :	I
Packing group (IATA) :	I
Packing group (ADN) :	I
Packing group (RID) :	I
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : TC1 Special provision (ADR) : 274 Limited quantities (ADR) : 0 Excepted quantities (ADR) : E0 Packing instructions (ADR) : P602 Mixed packing provisions (ADR) : MP8, MP17 Portable tank and bulk container instructions (ADR) : T20 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L10CH Tank special provisions (ADR) : TU14, TU15, TE19, TE21 Vehicle for tank carriage : AT Transport category (ADR) : 1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV1, CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S14 Hazard identification number (Kemler No.) : 668 Orange plates : Tunnel restriction code (ADR) : C/D EAC code : 2XE APP code : B
- Transport by sea
Special provision (IMDG) : 274 Limited quantities (IMDG) : 0 Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P602 Tank instructions (IMDG) : T20 Tank special provisions (IMDG) : TP2, TP13 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : D Stowage and handling (IMDG) : SW2 MFAG-No : 154
- Air transport
PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : Forbidden PCA max net quantity (IATA) : Forbidden CAO packing instructions (IATA) : Forbidden CAO max net quantity (IATA) : Forbidden ERG code (IATA) : 6C
- Inland waterway transport
Classification code (ADN) : TC1 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 0 Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : TC1 Special provision (RID) : 274 Limited quantities (RID) : 0 Excepted quantities (RID) : E0 Packing instructions (RID) : P602 Mixed packing provisions (RID) : MP8, MP17 Portable tank and bulk container instructions (RID) : T20 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L10CH Special provisions for RID tanks (RID) : TU14, TU15, TU38, TE21, TE22 Transport category (RID) : 1 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Hazard identification number (RID) : 668
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Sulfur monochloride is not on the REACH Candidate List Sulfur monochloride is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 3; WGK No 2277) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1 Skin Corr. 1A Skin corrosion/irritation, Category 1A H301 Toxic if swallowed H314 Causes severe skin burns and eye damage H332 Harmful if inhaled H400 Very toxic to aquatic life R14 Reacts violently with water R20 Harmful by inhalation R25 Toxic if swallowed R29 Contact with water liberates toxic gas R35 Causes severe burns R50 Very toxic to aquatic organisms C Corrosive N Dangerous for the environment T Toxic Xn Harmful