CHLORO ACETIC ACID (di) (dichloroacetic acid) |
| Synonyms : dichloroacetic acid |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | CHLORO ACETIC ACID (di) (dichloroacetic acid) | ||
| Catalogue No. : | AL1250 | Product form : | Substance |
| CAS Number : | 79-43-6 | EC Number : | 201-207-0 |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 29154020 | |
| Synonyms : | dichloroacetic acid | ||
| Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Acute toxicity (dermal), Category 3 H311 Skin corrosion/irritation, Category 1 H314 Carcinogenicity, Category 2 H351 Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Full text of classification categories and H statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Not classified | |
| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS05
 GHS06
 GHS08
 GHS09
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H311 - Toxic in contact with skin H314 - Causes severe skin burns and eye damage H351 - Suspected of causing cancer H400 - Very toxic to aquatic life |
| Precautionary statements (CLP) : | P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Not applicable | |||
| CAS No. : | 79-43-6 | ||
| EC No. : | 201-207-0 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice. |
| First-aid measures after skin contact : | Take off contaminated clothing. Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. |
| First-aid measures after eye contact : | Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Do not induce vomiting because of corrosive effects. If you feel unwell, seek medical advice. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after skin contact : Toxic in contact with skin. Chronic symptoms : Suspected carcinogen. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Water spray. Dry chemical, CO2, dry sand, or alcohol-resistant foam. |
| Unsuitable extinguishing media : | Carbon dioxide (CO2). Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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| Special procedures : | No additional information available |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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| Protective equipment | Use personal protective equipment as required |
| Emergency procedures | Stop release. Ventilate area. |
6.2 Environmental precautions |
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| Very toxic to aquatic life. | |
6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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| Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Precautions for safe handling : | Avoid contact with skin, eyes and clothing. Do not breathe vapours. Handle carefully. |
| Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear appropriate mask |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid |
| Molecular mass : | 128.94 g/mol |
| Colour : | Colourless to Light yellow. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | 1.2 at 129 g/l at 20 °C |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | 9 - 11 °C |
| Freezing point : | No data available |
| Boiling point : | 194 °C |
| Flash point : | 113 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | No data available |
| Vapour pressure : | No data available Vapour pressure at 50 °C : 0.1 |
| Relative vapour density at 20°C : | 4.45 |
| Density : | 1.563 g/cm3 at 25 °C |
| Solubility : | No data available |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| May be corrosive to metals. Heating may cause a fire. | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Direct sunlight. Overheating. Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
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| Oxidizing agent. Strong acids. Strong bases. | |
10.6 Hazardous decomposition products |
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| No additional information available |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Dermal: Toxic in contact with skin. |
| Skin corrosion/irritation : | Causes severe skin burns and eye damage. pH: 1.2 at 129 g/l at 20 °C |
| Serious eye damage/irritation : | Serious eye damage, category 1, implicit pH: 1.2 at 129 g/l at 20 °C |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Suspected of causing cancer. |
| Reproductive toxicity : | Not classified |
| Specific target organ toxicity (single exposure) : | Not classified |
| Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Additional Info : | No additional information available |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1764 |
| UN-No. (IMDG) : | 1764 |
| UN-No. (IATA) : | 1764 |
| UN-No. (ADN) : | 1764 |
| UN-No. (RID) : | 1764 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | DICHLOROACETIC ACID |
| Proper Shipping Name (IMDG) : | DICHLOROACETIC ACID |
| Proper Shipping Name (IATA) : | DICHLOROACETIC ACID |
| Proper Shipping Name (ADN) : | DICHLOROACETIC ACID |
| Proper Shipping Name (RID) : | DICHLOROACETIC ACID |
| Transport document description (ADR) : | UN 1764, DICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IMDG) : | UN 1764, DICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (IATA) : | UN 1764, DICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (ADN) : | UN 1764, DICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS |
| Transport document description (RID) : | UN 1764, DICHLOROACETIC ACID, 8, II ENVIRONMENTALLY HAZARDOUS |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8 
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| IMDG | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| IATA | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| ADN | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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| RID | |
| Transport hazard class(es) : | 8 |
| Danger labels : | 8
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14.4. Packing group |
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| Packing group (ADR) : | II |
| Packing group (IMDG) : | II |
| Packing group (IATA) : | II |
| Packing group (ADN) : | II |
| Packing group (RID) : | II |
14.5. Environmental hazards |
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| Dangerous for the environment : | Yes |
| Marine pollutant : | Yes |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : C3 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T8 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X |
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| - Transport by sea | |
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Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B20 Tank instructions (IMDG) : T8 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : A |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L ERG code (IATA) : 8i |
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| - Inland waterway transport | |
| Not regulated | |
| - Rail transport | |
| Not regulated | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions Dichloroacetic acid Extra Pure is not on the REACH Candidate List Dichloroacetic acid Extra Pure is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to VwVwS, Annex 3; WGK No 243) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the pro |
| Denmark |
| Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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