SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	BENZOYL PEROXIDE (moistened with 25% water)
Catalogue No. :	AL0640	Product form :	Substance
CAS Number :	94-36-0	EC Number :	202-327-6
Grade :		EC Index Number :	617-008-00-0
Chemical Formula :	C14H10O4	HSN Code :	29163200
Synonyms :	Dibenzoyl peroxide / Benzoyl peroxide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Self-Reactive Substances and Mixtures, Type C H242 Serious eye damage/eye irritation, Category 2 H319 Sensitisation Skin, category 1 H317 Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R7 Xi; R36 R43 R1 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS02 GHS07
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H242 - Heating may cause a fire H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation
Precautionary statements (CLP) :	P220 - Keep away from clothing and other combustible materials P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P410 - Protect from sunlight P420 - Store separately
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		BENZOYL PEROXIDE (WITH 25% WATER) Extra Pure
CAS No. :		94-36-0
EC Index No. :		617-008-00-0
EC No. :		202-327-6
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Fire hazard :	Heating may cause a fire. Hazardous decomposition products in case of fire : Thermal dec
Explosion hazard :
5.3 Advice for firefighters
Protection during firefighting :	No additional information available

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
General measures :	No naked lights. No smoking. Remove ignition sources. Use special care to avoid static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Additional hazards when processed :	Hazardous waste due to potential risk of explosion.
Precautions for safe handling :	Do not breathe vapours. Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes.
Hygiene measures :	Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Proper grounding procedures to avoid static electricity should be followed.
Storage conditions :	Keep in fireproof place. Store in a well-ventilated place. Keep cool.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid Colour
Colour :	white.
Odour :	faint odor of benzaldehyde.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	103 - 104 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	40 °C
Auto-ignition temperature :	80 °C
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	1.334 g/cm3
Solubility :	Water: Slightly soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	Explosive when dry.
Oxidising properties :	May intensify fire; oxidiser.
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Heating may cause a fire. Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Heat. Sparks. Open flame.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	May cause an allergic skin reaction.
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
Reproductive toxicity :	Not classified
Specific target organ toxicity (single exposure) :	Not classified
Specific target organ toxicity (repeated exposure) :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...
Additional information :	Clean up even minor leaks or spills if possible without unecessary risk. Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3104
UN-No. (IMDG) :	3104
UN-No. (IATA) :	3104
UN-No. (ADN) :	3104
UN-No. (RID) :	3104
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ORGANIC PEROXIDE TYPE C, SOLID
Proper Shipping Name (IMDG) :	ORGANIC PEROXIDE TYPE C, SOLID
Proper Shipping Name (IATA) :	ORGANIC PEROXIDE TYPE C, SOLID
Proper Shipping Name (ADN) :	ORGANIC PEROXIDE TYPE C, SOLID
Proper Shipping Name (RID) :	ORGANIC PEROXIDE TYPE C, SOLID
Transport document description (ADR) :	UN 3104, ORGANIC PEROXIDE TYPE C, SOLID, 5.2, Not applicable
Transport document description (IMDG) :	UN 3104, ORGANIC PEROXIDE TYPE C, SOLID, 5.2, Not applicable
Transport document description (IATA) :	UN 3104, ORGANIC PEROXIDE TYPE C, SOLID, 5.2, Not applicable
Transport document description (ADN) :	UN 3104, ORGANIC PEROXIDE TYPE C, SOLID, 5.2, Not applicable
Transport document description (RID) :	UN 3104, ORGANIC PEROXIDE TYPE C, SOLID, 5.2, Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	5.2
Danger labels :	5.2
IMDG
Transport hazard class(es) :	5.2
Danger labels :	5.2
IATA
Transport hazard class(es) :	5.2
Danger labels :	5.2
ADN
Transport hazard class(es) :	5.2
Danger labels :	5.2
RID
Transport hazard class(es) :	5.2
Danger labels :	5.2
14.4. Packing group
Packing group (ADR) :	Not applicable
Packing group (IMDG) :	Not applicable
Packing group (IATA) :	Not applicable
Packing group (ADN) :	Not applicable
Packing group (RID) :	Not applicable
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : P1 Special provision (ADR) : 122, 274 Limited quantities (ADR) : 100g Excepted quantities (ADR) : E0 Packing instructions (ADR) : P520 Mixed packing provisions (ADR) : MP4 Transport category (ADR) : 1 Special provisions for carriage - Packages (ADR) : V1 Special provisions for carriage - Loading, unloading and handling (ADR) : CV15, CV20, CV22, CV24 Special provisions for carriage - Operation (ADR) : S8, S18 Tunnel restriction code (ADR) : D EAC code : 1WE
- Transport by sea
Special provision (IMDG) : 122, 195, 274 Limited quantities (IMDG) : 100 g Excepted quantities (IMDG) : E0 Packing instructions (IMDG) : P520 EmS-No. (Fire) : F-J EmS-No. (Spillage) : S-R Stowage category (IMDG) : D Stowage and handling (IMDG) : SW1 Segregation (IMDG) : SG35, SG36 MFAG-No : 146
- Air transport
PCA Excepted quantities (IATA) : E0 PCA Limited quantities (IATA) : Forbidden PCA limited quantity max net quantity (IATA) : Forbidden PCA packing instructions (IATA) : 570 PCA max net quantity (IATA) : 5kg CAO packing instructions (IATA) : 570 CAO max net quantity (IATA) : 10kg Special provision (IATA) : A20, A150 ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : P1 Special provisions (ADN) : 122, 274 Limited quantities (ADN) : 100 g Excepted quantities (ADN) : E0 Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : P1 Special provision (RID) : 122, 274 Limited quantities (RID) : 100g Excepted quantities (RID) : E0 Packing instructions (RID) : P520 Mixed packing provisions (RID) : MP4 Transport category (RID) : 1 Special provisions for carriage – Packages (RID) : W7 Special provisions for carriage – Loading and unloading (RID) : CW22, CW24, CW29 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 539
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Benzoyl peroxide is not on the REACH Candidate List Benzoyl peroxide is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 1100) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Denmark Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks
Denmark
Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 ; Emergency management guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information
Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Self-react. C Self-Reactive Substances and Mixtures, Type C Skin Sens. 1 Sensitisation — Skin, category 1 H242 Heating may cause a fire H317 May cause an allergic skin reaction H319 Causes serious eye irritation R1 Dep