HYDROGEN PEROXIDE SOLUTION AR |
Synonyms : Dihydrogen dioxide; Hydrogen dioxide; Hydroperoxide |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
|||
---|---|---|---|
1.1 Product identifier |
|||
Chemical Name : | HYDROGEN PEROXIDE (100 Vol.) AR (30% w/v H2O2) | ||
Catalogue No. : | AL2470 | Product form : | Mixture |
CAS Number : | 7722-84-1 | EC Number : | |
Grade : | EC Index Number : | ||
Chemical Formula : | H2O2 | HSN Code : | 28470000 |
Synonyms : | Dihydrogen dioxide | ||
Chemical Structure : | H2O2 | ||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
|||
Use of the substance/mixture : | Industrial;For professional use only | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
|||
Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
||
1.4 Emergency Contact Details |
|||
Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
|
---|---|
2.1 Classification of the substance or mixture |
|
Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Serious eye damage/eye irritation, Category 1 H318 Acute toxicity (oral), Category 4 H302 Full text of classification categories and H statements : see section 16 |
|
Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
|
Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS05 GHS07 |
Signal word (CLP) : | Danger |
Hazard statements (CLP) : | H302 - Harmful if swallowed H318 - Causes serious eye damage |
Precautionary statements (CLP) : | P280 - Wear eye protection, face protection, protective clothing, protective gloves P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
2.3 Other hazards |
|
Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
|||
---|---|---|---|
3.1. Substance |
|||
Not applicable | |||
CAS No. : | 7722-84-1 | ||
3.2. Mixture |
|||
Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
Water | (CAS No) 7732-18-5 (EC no) 231-791-2 | 50 - 75 | Not classified |
Hydrogen peroxide | (CAS No) 7722-84-1 (EC no) 231-765-0 (EC index no) 008-003-00-9 | 25 - 50 | Eye Dam. 1, H318 Acute Tox. 4 (Oral), H302 |
Acetanilide (CAS No) 103-84-4 (EC no) 203-150-7 | 0.01 - 1 | Acute Tox. 4 (Oral), H302 | |
Full text of H-phrases: see section 16 |
SECTION 4: First aid measures |
|
---|---|
4.1 Description of first aid measures |
|
First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. If you feel unwell, seek medical advice. |
First-aid measures after skin contact : | Take off contaminated clothing. Gently wash with plenty of soap and water. Get immediate medical advice/attention. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. |
First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
|
Symptoms relating to use : | Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard. |
4.3 Indication of any immediate medical attention and special treatment needed |
|
General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
|
---|---|
5.1 Extinguishing media |
|
Suitable extinguishing media : | Dry chemical, CO2, or water spray or regular foam. |
Unsuitable extinguishing media : | Carbon dioxide (CO2). |
5.2 Special hazards arising from the substance or mixture |
|
Special procedures : | No additional information available |
5.3 Advice for firefighters |
|
Protection during firefighting : | Do not attempt to take action without suitable protective equipment. |
SECTION 6: Accidental release measures |
|
---|---|
6.1 Personal precautions, protective equipment and emergency procedures |
|
6.1.1. For non-emergency personnel |
|
Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
|
Protective equipment | Use personal protective equipment as required |
Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
|
Avoid release to the environment. | |
6.3 Methods and material for containment and cleaning up |
|
Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
|
Reference : | No additional information available |
SECTION 7: Handling and storage |
|
---|---|
7.1 Precautions for safe handling |
|
Precautions for safe handling : | Avoid contact with skin and eyes. |
Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
|
Storage conditions : | Store in a well-ventilated place. Keep container tightly closed. |
7.3 Specific end use(s) |
|
No additional information available |
SECTION 8: Exposure controls/personal protection |
|
---|---|
8.1 Control parameters |
|
No additional information available | |
8.2 Exposure controls |
|
Hand protection : | protective gloves |
Eye protection : | |
Skin and body protection : | |
Respiratory protection : | Wear respiratory protection |
SECTION 9: Physical and chemical properties |
|
---|---|
9.1 Information on basic physical and chemical properties |
|
Physical state : | Liquid |
Molecular mass : | 34.1 g/mol |
Colour : | Clear Colorless. |
Odour : | slight acrid odor. |
Odour threshold : | No data available |
pH value : | 6 - 8 at 25 °C |
Relative evaporation rate (butylacetate=1) : | No data available |
Melting point : | No data available |
Freezing point : | No data available |
Boiling point : | No data available |
Flash point : | No data available |
Auto-ignition temperature : | No data available |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | No data available |
Vapour pressure : | 25 mm Hg at 300C |
Relative vapour density at 20°C : | 1.17 |
Density : | 1.11 g/cm3 |
Solubility : | Water: Infinitely soluble |
Log Pow : | No data available |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | No data available |
9.2 Other information |
|
No additional information available |
SECTION 10: Stability and reactivity |
|
---|---|
10.1 Reactivity |
|
No additional information available | |
10.2 Chemical stability |
|
Stable under normal conditions of use. | |
10.3 Possibility of hazardous reactions |
|
No additional information available | |
10.4 Conditions to avoid |
|
Direct sunlight. Moisture. | |
10.5 Incompatible materials |
|
No additional information available | |
10.6 Hazardous decomposition products |
|
No additional information available |
SECTION 11: Toxicological information |
|
---|---|
11.1 Information on toxicological effects |
|
Acute toxicity : | Oral: Harmful if swallowed. ATE CLP (oral) 500 mg/kg bodyweight |
Skin corrosion/irritation : | Not classified pH: 6 - 8 at 25 °C |
Serious eye damage/irritation : | Causes serious eye damage. pH: 6 - 8 at 25 °C |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Not classified |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | Not classified |
Specific target organ toxicity (repeated exposure) : | Not classified |
Aspiration hazard : | Not classified |
Potential adverse human health effects and symptoms : | Harmful if swallowed. |
SECTION 12: Ecological information |
|
---|---|
12.1 Toxicity |
|
Toxicity information : | No additional information available |
12.2 Persistence - degradability |
|
Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
|
Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
|
Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
|
No additional information available | |
12.6 Other adverse effects |
|
Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
|
---|---|
13.1 Waste treatment methods |
|
Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
SECTION 14: Transport information |
|
---|---|
In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
|
UN-No. (ADR) : | 2014 |
UN-No. (IMDG) : | 2014 |
UN-No. (IATA) : | 2014 |
UN-No. (ADN) : | 2014 |
UN-No. (RID) : | 2014 |
14.2. UN proper shipping name |
|
Proper Shipping Name (ADR) : | HYDROGEN PEROXIDE, AQUEOUS SOLUTION |
Proper Shipping Name (IMDG) : | HYDROGEN PEROXIDE, AQUEOUS SOLUTION |
Proper Shipping Name (IATA) : | HYDROGEN PEROXIDE, AQUEOUS SOLUTION |
Proper Shipping Name (ADN) : | HYDROGEN PEROXIDE, AQUEOUS SOLUTION |
Proper Shipping Name (RID) : | HYDROGEN PEROXIDE, AQUEOUS SOLUTION |
Transport document description (ADR) : | UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II |
Transport document description (IMDG) : | UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II |
Transport document description (IATA) : | UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II |
Transport document description (ADN) : | UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II |
Transport document description (RID) : | UN 2014, HYDROGEN PEROXIDE, AQUEOUS SOLUTION, 5.1 (8), II |
14.3. Transport hazard class(es) |
|
ADR | |
Transport hazard class(es) : | 5.1 (8) |
Danger labels : | 5.1, 8 |
IMDG | |
Transport hazard class(es) : | 5.1 (8) |
Danger labels : | 5.1, 8 |
IATA | |
Transport hazard class(es) : | 5.1 (8) |
Danger labels : | 5.1, 8 |
ADN | |
Transport hazard class(es) : | 5.1 (8) |
Danger labels : | 5.1, 8 |
RID | |
Transport hazard class(es) : | 5.1 (8) |
Danger labels : | 5.1, 8 |
14.4. Packing group |
|
Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
|
Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
|
- Overland transport | |
Classification code (ADR) : OC1 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P504, IBC02 Special packing provisions (ADR) : PP10, B5 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2, TP6, TP24 Tank code (ADR) : L4BV(+) Tank special provisions (ADR) : TU3, TC2, TE8, TE11, TT1 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24 Hazard identification number (Kemler No.) : 58 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2P |
|
- Transport by sea | |
Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P504 Packing provisions (IMDG) : PP10 IBC packing instructions (IMDG) : IBC02 IBC special provisions (IMDG) : B5 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2, TP6, TP24 EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q Stowage category (IMDG) : D Stowage and handling (IMDG) : SW1 Segregation (IMDG) : SG16, SG59, SG72 MFAG-No : 140 |
|
- Air transport | |
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y540 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 550 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 554 CAO max net quantity (IATA) : 5L ERG code (IATA) : 5C |
|
- Inland waterway transport | |
Not regulated | |
- Rail transport | |
Not regulated | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
|
Not applicable |
SECTION 15: Regulatory information |
---|
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances. |
15.1.2. National regulations |
Germany |
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
||||||
---|---|---|---|---|---|---|
|