SODIUM PEROXIDE GRANULAR AR/ACS

SODIUM PEROXIDE GRANULAR AR/ACS

Synonyms : Sodium superoxide

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : SODIUM PEROXIDE (granular) AR
Catalogue No. : AL4232 Product form : Substance
CAS Number : 1313-60-6 EC Number : 215-209-4
Grade : EC Index Number : 011-003-00-1
Chemical Formula : HSN Code : 28153000
Synonyms : Sodium superoxide
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids,
Category 1
H271
Skin corrosion/irritation,
Category 1A
H314
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
O; R8
C; R35
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS03GHS03 GHS05GHS05
Signal word (CLP) : Danger
Hazard statements (CLP) : H271 - May cause fire or explosion; strong oxidiser.
H314 - Causes severe skin burns and eye damage.
Precautionary statements (CLP) : P220 - Keep/Store away from clothing and other combustible materials.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : SODIUM PEROXIDE (GRANULAR) AR/ACS
CAS No. : 1313-60-6
EC Index No. : 011-003-00-1
EC No. : 215-209-4
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.
First-aid measures after skin contact : IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of
water before removing clothes. Take off immediately all contaminated clothing.
Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Dry powder.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : May cause fire or explosion; strong oxidiser.
Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing
risk of burns and injuries.
5.3 Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : No open flames. No smoking.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Stop release.
6.2 Environmental precautions
Do not allow contact with water.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Hazardous waste due to potential risk of explosion.
Precautions for safe handling : Take any precaution to avoid mixing with combustibles... Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures : Wash hands, forearms and face thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Keep in fireproof place. Store in a well-ventilated place. Keep cool.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or face shield
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 77.98 g/mol
Colour : Pale yellow.
Odour : odourless.
Odour threshold : No data available
pH value : 12.8
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 460 °C
Freezing point : No data available
Boiling point : 657 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 2.81 g/cm3
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : May cause fire or explosion; strong oxidiser.
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
May cause fire or explosion; strong oxidiser.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Heat. Sparks. Overheating. Open flame.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 12.8
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 12.8
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information : Hazardous waste due to potential risk of explosion.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1504
UN-No. (IMDG) : 1504
UN-No. (IATA) : 1504
UN-No. (ADN) : 1504
UN-No. (RID) : 1504
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM PEROXIDE
Proper Shipping Name (IMDG) : SODIUM PEROXIDE
Proper Shipping Name (IATA) : SODIUM PEROXIDE
Proper Shipping Name (ADN) : SODIUM PEROXIDE
Proper Shipping Name (RID) : SODIUM PEROXIDE
Transport document description (ADR) : UN 1504, SODIUM PEROXIDE, 5.1, I
Transport document description (IMDG) : UN 1504, SODIUM PEROXIDE, 5.1, I
Transport document description (IATA) : UN 1504, SODIUM PEROXIDE, 5.1, I
Transport document description (ADN) : UN 1504, SODIUM PEROXIDE, 5.1, I
Transport document description (RID) : UN 1504, SODIUM PEROXIDE, 5.1, I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 5.1
Danger labels : 5.1
IMDG
Transport hazard class(es) : 5.1
Danger labels : 5.1
IATA
Transport hazard class(es) : 5.1
Danger labels : 5.1
ADN
Transport hazard class(es) : 5.1
Danger labels : 5.1
RID
Transport hazard class(es) : 5.1
Danger labels : 5.1
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : O2
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P503, IBC05
Mixed packing provisions (ADR) : MP2
Transport category (ADR) : 1
Special provisions for carriage - Packages
(ADR)
: V10
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV24
Special provisions for carriage - Operation
(ADR)
: S20
Tunnel restriction code (ADR) : E
EAC code : 1W
- Transport by sea
Limited quantities (IMDG) : 0
Excepted quantities (IMDG) : E0
Packing instructions (IMDG) : P503
IBC packing instructions (IMDG) : IBC05
IBC special provisions (IMDG) : B1
EmS-No. (Fire) : F-G
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : C
Stowage and handling (IMDG) : H1
Segregation (IMDG) : SG16, SG35, SG59, SG26, SG36
MFAG-No : 144
- Air transport
PCA Excepted quantities (IATA) : E0
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : Forbidden
PCA max net quantity (IATA) : Forbidden
CAO packing instructions (IATA) : 561
CAO max net quantity (IATA) : 15kg
Special provisions (IATA) : A1
ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : O2
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : O2
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P503, IBC05
Mixed packing provisions (RID) : MP2
Transport category (RID) : 1
Special provisions for carriage – Packages
(RID)
: W10
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW24
Hazard identification number (RID) : 55
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
SODIUM PEROXIDE (GRANULAR) AR/ACS is not on the REACH Candidate List
SODIUM PEROXIDE (GRANULAR) AR/ACS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 1, Slightly hazardous to water (Classification according to
AwSV; ID No. 383)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Ox. Sol. 1 Oxidising Solids, Category 1
Skin Corr. 1A Skin corrosion/irritation, Category 1A
H271 May cause fire or explosion; strong oxidiser.
H314 Causes severe skin burns and eye damage.
R35 Causes severe burns
R8 Contact with combustible material may cause fire
C Corrosive
O Oxidising