2-NAPHTHOL For Synthesis

2-NAPHTHOL For Synthesis

Synonyms : β-Naphthol; 2-Hydroxynaphthalene

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : b-NAPHTHOL
Catalogue No. : AL3166 Product form : Substance
CAS Number : 135-19-3 EC Number : 205-182-7
Grade : EC Index Number : 604-007-00-5
Chemical Formula : HSN Code : 29071520
Synonyms : β-Naphthol / 2-Hydroxynaphthalene
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.),
Category 4
H332
Acute toxicity (oral),
Category 4
H302
Hazardous to the aquatic
environment Acute
Hazard, Category 1
H400
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Xn; R20/22
N; R50
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS07GHS07 GHS09GHS09
Signal word (CLP) : -
Hazard statements (CLP) : H302+H332 - Harmful if swallowed or if inhaled
H400 - Very toxic to aquatic life
Precautionary statements (CLP) : P273 - Avoid release to the environment
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : 2-NAPHTHOL FOR SYNTHESIS
CAS No. : 135-19-3
EC Index No. : 604-007-00-5
EC No. : 205-182-7
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries after inhalation : Harmful if inhaled.
Symptoms/injuries after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : No additional information available

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
No additional information available
6.2 Environmental precautions
Very toxic to aquatic life.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Clean up immediately by sweeping or vacuum.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 144.17 g/mol
Colour : Off white flakes.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 121 - 122
Freezing point : No data available
Boiling point : 285 - 286
Flash point : 153 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : 13 mm Hg at 145.5 °C
Relative vapour density at 20°C : 4.98
Density : 1.22 g/cm3
Solubility : Water: Slightly soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions of use.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Inhalation: Harmful if inhaled. Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3077
UN-No. (IMDG) : 3077
UN-No. (IATA) : 3077
UN-No. (ADN) : 3077
UN-No. (RID) : 3077
14.2. UN proper shipping name
Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (ADN) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 3077, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 9
Danger labels : 9
IMDG
Transport hazard class(es) : 9
Danger labels : 9
IATA
Transport hazard class(es) : 9
Danger labels : 9
ADN
Transport hazard class(es) : 9
Danger labels : 9
RID
Transport hazard class(es) : 9
Danger labels : 9
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M7
Special provision (ADR) : 274, 335, 601, 375
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : PP12, B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1, BK1, BK2
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAV, LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V13
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13
Hazard identification number (Kemler No.) : 90
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2Z
- Transport by sea
Special provision (IMDG) : 274, 335, 966, 967, 969
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002, LP02
Packing provisions (IMDG) : PP12
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1, BK1, BK2, BK3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW23
MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y956
PCA limited quantity max net quantity
(IATA)
: 30kgG
PCA packing instructions (IATA) : 956
PCA max net quantity (IATA) : 400kg
CAO packing instructions (IATA) : 956
CAO max net quantity (IATA) : 400kg
Special provision (IATA) : A97, A158, A179, A197
ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M7
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T* B**
Equipment required (ADN) : PP, A
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : M7
Special provision (RID) : 274, 335, 375, 601
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : PP12, B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1, BK1, BK2
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAV, LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W13
Special provisions for carriage – Bulk
(RID)
: VC1, VC2
Special provisions for carriage – Loading
and unloading (RID)
: CW13, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
2-NAPHTHOL FOR SYNTHESIS is not on the REACH Candidate List
2-NAPHTHOL FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to
VwVwS, Annex 2; WGK No 1263)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
H302 Harmful if swallowed
H332 Harmful if inhaled
H400 Very toxic to aquatic life
R20/22 Harmful by inhalation and if swallowed
R50 Very toxic to aquatic organisms
N Dangerous for the environment
Xn Harmful