SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	PHENOL DISULPHONIC ACID
Catalogue No. :	AL3467	Product form :	Mixture
CAS Number :	1333-39-7	EC Number :	215-587-0
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	38220090
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial;For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
Muta.Cat.3; R68 T; R23/24/25 Xn; R48/20/21/22 C; R35 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
CAS No. :		1333-39-7
EC No. :		215-587-0
3.2. Mixture
Name	Product identifier	%	Classification according to Directive 67/548/EEC	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Sulphuric acid	(CAS No) 7664-93- 9 (EC no) 231-639-5 (EC index no) 016- 020-00-8	75 - 99	C; R35	Skin Corr. 1A, H314 Eye Dam. 1, H318
Phenol	(CAS No) 108-95-2 (EC no) 203-632-7 (EC index no) 604- 001-00-2	10 - 15	Muta.Cat.3; R68 T; R23/24/25 Xn; R48/20/21/22 C; R34	Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 Eye Dam. 1, H318 Muta. 2, H341 STOT RE 2, H373
Full text of R- and H-phrases: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact :	Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER or doctor/physician if you feel unwell. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries : Causes severe skin burns and eye damage. Suspected of causing genetic defects. Causes damage to organs. Symptoms/injuries after ingestion : Swallowing a small quantity of this material will result in serious health hazard.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use extinguishing media containing water.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Do not get in eyes, on skin, or on clothing.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Store away from other materials. Minimize generation of dust. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing. Obtain special instructions before use. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understo
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations.
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Yellow to brown.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Density :	1.4 g/cm3
Solubility :	Water: Reacts with water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Toxic by inhalation, in contact with skin and if swallowed. Irritation : Not classified Corrosivity : Causes severe burns. Sensitisation : Not classified Repeated dose toxicity : Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed. Carcinogenicity : Not classified Mutagenicity : Possible risk of irreversible effects. Toxicity for reproduction : Not classified Potential adverse human health effects and sympto
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :
Germ cell mutagenicity :
Carcinogenicity :
Potential adverse human health effects and symptoms :	Harmful if swallowed.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1760
UN-No. (IMDG) :	1760
UN-No. (IATA) :	1760
UN-No. (ADN) :	1760
UN-No. (RID) :	1760
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (IMDG) :	CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (IATA) :	CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (ADN) :	CORROSIVE LIQUID, N.O.S.
Proper Shipping Name (RID) :	CORROSIVE LIQUID, N.O.S.
Transport document description (ADR) :	UN 1760, CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (IMDG) :	UN 1760, CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (IATA) :	UN 1760, CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (ADN) :	UN 1760, CORROSIVE LIQUID, N.O.S., 8, II
Transport document description (RID) :	UN 1760, CORROSIVE LIQUID, N.O.S., 8, II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	8
Danger labels :	8
IMDG
Transport hazard class(es) :	8
Danger labels :	8
IATA
Transport hazard class(es) :	8
Danger labels :	8
ADN
Transport hazard class(es) :	8
Danger labels :	8
RID
Transport hazard class(es) :	8
Danger labels :	8
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : C9 Special provision (ADR) : 274 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T11 Portable tank and bulk container special provisions (ADR) : TP2, TP27 Tank code (ADR) : L4BN Vehicle for tank carriage : AT Transport category (ADR) : 2 Hazard identification number (Kemler No.) : 80 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2X APP code : B
- Transport by sea
Special provision (IMDG) : 274 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T11 Tank special provisions (IMDG) : TP2, TP27 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-B Stowage category (IMDG) : B Stowage and handling (IMDG) : SW2 MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y840 PCA limited quantity max net quantity (IATA) : 0.5L PCA packing instructions (IATA) : 851 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 855 CAO max net quantity (IATA) : 30L Special provision (IATA) : A3 ERG code (IATA) : 8L
- Inland waterway transport
Classification code (ADN) : C9 Special provisions (ADN) : 274 Limited quantities (ADN) : 1 L Excepted quantities (ADN) : E2 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : C9 Special provision (RID) : 274 Limited quantities (RID) : 1L Excepted quantities (RID) : E2 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T11 Portable tank and bulk container special provisions (RID) : TP2, TP27 Tank codes for RID tanks (RID) : L4BN Transport category (RID) : 2 Colis express (express parcels) (RID) : CE6 Hazard identification number (RID) : 80
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 1, slightly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Muta. 2 Germ cell mutagenicity, Category 2 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Corr. 1B Skin corrosion/irritation, Category 1B STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2 H301 Toxic if swallowed H311 Toxic in contact with skin H314 Causes severe skin burns and eye damage H318 Causes serious eye damage H331 Toxic if inhaled H341 Suspected of causing genetic defects H373 May cause damage to organs through prolonged or repeated exposure R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R35 Causes severe burns R48/20/21/22 Harmful: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed R68 Possible risk of irreversible effects C Corrosive T Toxic Xn Harmful