2,4,6-TRIMETHYL PYRIDINE For Synthesis |
| Synonyms : 2,4,6-Collidine |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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| Chemical Name : | 2,4,6-TRIMETHYL PYRIDINE | ||
| Catalogue No. : | AL4677 | Product form : | Substance |
| CAS Number : | 108-75-8 | EC Number : | 203-613-3 |
| Grade : | EC Index Number : | ||
| Chemical Formula : | HSN Code : | 29333919 | |
| Synonyms : | sym-Collidine / 2,4,6-Collidine | ||
| Chemical Structure : |
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1.2 Relevant identified uses of the substance or mixture and uses advised against |
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| Use of the substance/mixture : | Laboratory chemicals, Manufacture of substances | ||
| Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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| Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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| Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
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SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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| Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
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Flammable liquids, Category 3 H226 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 4 H332 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H335 Full text of hazard classes and H-statements : see section 16 |
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| Classification according to Directive 67/548/EEC or 1999/45/EC | |
| Xn; R20/21/22 Xi; R36/37/38 R10 Full text of R-phrases: see section 16 |
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| Adverse physicochemical, human health and environmental effects | |
| No additional information available | |
2.2 Label elements |
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| Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
| Hazard pictograms (CLP) : |
 GHS02
 GHS06
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| Signal word (CLP) : | Danger |
| Hazard statements (CLP) : | H226 - Flammable liquid and vapour. H302+H332 - Harmful if swallowed or if inhaled H311 - Toxic in contact with skin. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. |
| Precautionary statements (CLP) : | P261 - Avoid breathing vapours, dust, fume, gas. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 - Call a doctor if you feel unwell. |
2.3 Other hazards |
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| Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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| Name : | 2,4,6-TRIMETHYL PYRIDINE For Synthesis | ||
| CAS No. : | 108-75-8 | ||
| EC No. : | 203-613-3 | ||
| Full text of R- and H-phrases: see section 16 | |||
3.2. Mixture |
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| Not applicable | |||
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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| First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
| First-aid measures after skin contact : | Wash with plenty of water/…. Wash contaminated clothing before reuse. Get medical advice/attention. |
| First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention. |
| First-aid measures after ingestion : | Rinse mouth. Call a POISON CENTER/doctor if you feel unwell. |
4.2 Most important symptoms and effects, both acute and delayed |
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| Symptoms relating to use : | Symptoms/effects after inhalation : May cause respiratory irritation. Symptoms/effects after skin contact : Harmful in contact with skin. Causes skin irritation. Symptoms/effects after eye contact : Causes serious eye irritation. Symptoms/effects after ingestion : Harmful if swallowed. |
4.3 Indication of any immediate medical attention and special treatment needed |
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| General information : | No additional information available |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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| Suitable extinguishing media : | Carbon dioxide. Dry powder. Foam. Water spray. |
| Unsuitable extinguishing media : | Do not use extinguishing media containing water. |
5.2 Special hazards arising from the substance or mixture |
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| Fire hazard : | Flammable liquid and vapour. |
| Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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| Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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| General measures : | Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. |
6.1.1. For non-emergency personnel |
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| Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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6.2 Environmental precautions |
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6.3 Methods and material for containment and cleaning up |
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| Methods for cleaning up : | |
6.4 Reference to other sections |
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| Reference : | |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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| Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
| Precautions for safe handling : | Avoid contact with skin and eyes. Take precautionary measures against static discharge. Use only non-sparking tools. Keep away from sources of ignition - No smoking. Use only outdoors or in a well-ventilated area. Do not breathe vapours. |
| Hygiene measures : | Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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| Technical measures : | Proper grounding procedures to avoid static electricity should be followed. Ground/bond container and receiving equipment. |
| Storage conditions : | Keep container tightly closed. Store in a well-ventilated place. |
7.3 Specific end use(s) |
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| No additional information available | |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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| No additional information available | |
8.2 Exposure controls |
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| Hand protection : | Protective gloves |
| Eye protection : | Chemical goggles or safety glasses |
| Skin and body protection : | Wear suitable protective clothing |
| Respiratory protection : | Wear respiratory protection. |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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| Physical state : | Liquid Colour |
| Colour : | Clear Colorless to light yellow. |
| Odour : | No data available |
| Odour threshold : | No data available |
| pH value : | No data available |
| Relative evaporation rate (butylacetate=1) : | No data available |
| Melting point : | -44 °C |
| Freezing point : | No data available |
| Boiling point : | 171 - 172 °C |
| Flash point : | 55 °C |
| Auto-ignition temperature : | No data available |
| Decomposition temperature : | No data available |
| Flammability (solid, gas) : | Flammable liquid and vapour. |
| Vapour pressure : | No data available |
| Relative vapour density at 20°C : | No data available |
| Density : | 0.917 g/ml at 25°C |
| Solubility : | No data available |
| Log Pow : | No data available |
| Viscosity, kinematic : | No data available |
| Viscosity, dynamic : | No data available |
| Explosive properties : | No data available |
| Oxidising properties : | No data available |
| Explosive limits : | No data available |
9.2 Other information |
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| No additional information available | |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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| No additional information available | |
10.2 Chemical stability |
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| Stable under normal conditions. | |
10.3 Possibility of hazardous reactions |
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| No additional information available | |
10.4 Conditions to avoid |
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| Open flame. Heat. Sparks. | |
10.5 Incompatible materials |
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| No additional information available | |
10.6 Hazardous decomposition products |
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| May release flammable gases. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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| Acute toxicity : | Oral: Harmful if swallowed. Dermal: Toxic in contact with skin. Inhalation: Harmful if inhaled. |
| Skin corrosion/irritation : | Causes skin irritation. |
| Serious eye damage/irritation : | Causes serious eye irritation. |
| Respiratory or skin sensitisation : | Not classified |
| Germ cell mutagenicity : | Not classified |
| Carcinogenicity : | Not classified |
| STOT-single exposure : | May cause respiratory irritation. |
| STOT-repeated exposure : | Not classified |
| Aspiration hazard : | Not classified |
| Potential adverse human health effects and symptoms : | Harmful if swallowed. Harmful in contact with skin. |
SECTION 12: Ecological information |
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12.1 Toxicity |
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| Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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| Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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| Bioaccumulative potential : | No additional information available |
12.4 Mobility in soil |
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| Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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| No additional information available | |
12.6 Other adverse effects |
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| Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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| Product/Packaging disposal recommendations : | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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| In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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| UN-No. (ADR) : | 1992 |
| UN-No. (IMDG) : | 1992 |
| UN-No. (IATA) : | 1992 |
| UN-No. (ADN) : | 1992 |
| UN-No. (RID) : | 1992 |
14.2. UN proper shipping name |
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| Proper Shipping Name (ADR) : | FLAMMABLE LIQUID, TOXIC, N.O.S. |
| Proper Shipping Name (IMDG) : | FLAMMABLE LIQUID, TOXIC, N.O.S. |
| Proper Shipping Name (IATA) : | FLAMMABLE LIQUID, TOXIC, N.O.S. |
| Proper Shipping Name (ADN) : | FLAMMABLE LIQUID, TOXIC, N.O.S. |
| Proper Shipping Name (RID) : | FLAMMABLE LIQUID, TOXIC, N.O.S. |
| Transport document description (ADR) : | UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), III |
| Transport document description (IMDG) : | UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), III |
| Transport document description (IATA) : | UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), III |
| Transport document description (ADN) : | UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), III |
| Transport document description (RID) : | UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S., 3 (6.1), III |
14.3. Transport hazard class(es) |
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| ADR | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1 
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| IMDG | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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| IATA | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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| ADN | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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| RID | |
| Transport hazard class(es) : | 3 (6.1) |
| Danger labels : | 3, 6.1
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14.4. Packing group |
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| Packing group (ADR) : | III |
| Packing group (IMDG) : | III |
| Packing group (IATA) : | III |
| Packing group (ADN) : | III |
| Packing group (RID) : | III |
14.5. Environmental hazards |
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| Dangerous for the environment : | No |
| Marine pollutant : | No |
| Other information : | No supplementary information available |
14.6. Special precautions for user |
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| - Overland transport | |
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Classification code (ADR) : FT1 Special provisions (ADR) : 274 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP1, TP28 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15 Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 36 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3WE APP code : A(fl) |
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| - Transport by sea | |
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Special provisions (IMDG) : 223, 274 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP1, TP28 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : A Properties and observations (IMDG) : Flammable toxic liquid which is not specified by name in this class or, on account of its characteristics, in some other class. Toxic if swallowed, by skin contact or by inhalation. MFAG-No : 131 |
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| - Air transport | |
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PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y343 PCA limited quantity max net quantity (IATA) : 2L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L Special provisions (IATA) : A3 ERG code (IATA) : 3P |
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| - Inland waterway transport | |
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Classification code (ADN) : FT1 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP, EX, TOX, A Ventilation (ADN) : VE01, VE02 Number of blue cones/lights (ADN) : 0 |
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| - Rail transport | |
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Classification code (RID) : FT1 Special provisions (RID) : 274 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP1, TP28 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28 Colis express (express parcels) (RID) : CE4 Hazard identification number (RID) : 36 |
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14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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| Not applicable | |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
| 15.1.1 EU-Regulations : |
| No REACH Annex XVII restrictions 2,4,6-TRIMETHYL PYRIDINE For Synthesis is not on the REACH Candidate List 2,4,6-TRIMETHYL PYRIDINE For Synthesis is not on the REACH Annex XIV List |
| 15.1.2. National regulations |
| Germany |
| 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Netherlands |
| SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed |
| Denmark |
| Class for fire hazard : Class II-1 Store unit : 5 liter Classification remarks : R10 guidelines for the storage of flammable liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product |
15.2 Chemical Safety Assessment |
| No additional information available |
SECTION 16: Other Information |
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