SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	CADMIUM NITRATE (4-hydrate)
Catalogue No. :	AL1031	Product form :	Substance
CAS Number :	10022-68-1	EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	28342990
Synonyms :	Nitric acid cadmium salt tetrahydrate
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, Category 2 H272 Acute toxicity (oral), Category 4 H302 Acute toxicity (dermal), Category 4 H312 Acute toxicity (inhal.), Category 4 H332 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.1; R45 O; R8 Xn; R20 Xn; R21 Xn; R22 N; R50/53 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS03 GHS07 GHS09
Signal word (CLP) :	Danger
Hazard statements (CLP) :	H272 - May intensify fire; oxidiser. H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P220 - Keep/Store away from clothing and other combustible materials. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation
2.3 Other hazards
Other hazards :	This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients
3.1. Substance
Name :		CADMIUM NITRATE TETRAHYDRATE Extra Pure
CAS No. :		10022-68-1
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
First-aid measures after skin contact :	Immediately call a POISON CENTER/doctor. Wash with plenty of water/…. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Call a POISON CENTER/doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after inhalation : Harmful if inhaled. Symptoms/effects after skin contact : Harmful in contact with skin. Symptoms/effects after ingestion : Harmful if swallowed.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard :
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Very toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures :	Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Solid
Molecular mass :	308.47 g/mol
Colour :	Colorless crystals.
Odour :	No data available
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	59.5 °C
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	Water: Soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	The substance or mixture is classified as oxidizin
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Oral: Harmful if swallowed. Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Not classified
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Not classified
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified
Aspiration hazard :	Not classified
Potential adverse human health effects and symptoms :	Harmful if swallowed. Harmful in contact with skin.

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	Ecology - water : Very toxic to aquatic life.
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
CADMIUM NITRATE TETRAHYDRATE Extra Pure (10022-68-1) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3087
UN-No. (IMDG) :	3087
UN-No. (IATA) :	3087
UN-No. (ADN) :	3087
UN-No. (RID) :	3087
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	OXIDIZING SOLID, TOXIC, N.O.S.
Proper Shipping Name (IMDG) :	OXIDIZING SOLID, TOXIC, N.O.S.
Proper Shipping Name (IATA) :	OXIDIZING SOLID, TOXIC, N.O.S.
Proper Shipping Name (ADN) :	OXIDIZING SOLID, TOXIC, N.O.S.
Proper Shipping Name (RID) :	OXIDIZING SOLID, TOXIC, N.O.S.
Transport document description (ADR) :	UN 3087, OXIDIZING SOLID, TOXIC, N.O.S., 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 3087, OXIDIZING SOLID, TOXIC, N.O.S., 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 3087, OXIDIZING SOLID, TOXIC, N.O.S., 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 3087, OXIDIZING SOLID, TOXIC, N.O.S., 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 3087, OXIDIZING SOLID, TOXIC, N.O.S., 5.1 (6.1), II ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
IMDG
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
IATA
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
ADN
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
RID
Transport hazard class(es) :	5.1 (6.1)
Danger labels :	5.1, 6.1
14.4. Packing group
Packing group (ADR) :	II
Packing group (IMDG) :	II
Packing group (IATA) :	II
Packing group (ADN) :	II
Packing group (RID) :	II
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : OT2 Special provisions (ADR) : 274 Limited quantities (ADR) : 1kg Excepted quantities (ADR) : E2 Packing instructions (ADR) : P002, IBC06 Mixed packing provisions (ADR) : MP2 Portable tank and bulk container instructions (ADR) : T3 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAN Tank special provisions (ADR) : TU3 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Packages (ADR) : V11 Special provisions for carriage - Loading, unloading and handling (ADR) : CV24, CV28 Hazard identification number (Kemler No.) : 56 Orange plates : Tunnel restriction code (ADR) : E EAC code : 1W
- Transport by sea
Special provisions (IMDG) : 274, 900 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC06 IBC special provisions (IMDG) : B21 Tank instructions (IMDG) : T3 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-Q Stowage category (IMDG) : B Segregation (IMDG) : SG38, SG49, SG60 Properties and observations (IMDG) : Toxic if swallowed, by skin contact or by dust inhalation. Should be handled with care to minimize exposure, particularly to dust. MFAG-No : 141
- Air transport
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y543 PCA limited quantity max net quantity (IATA) : 1kg PCA packing instructions (IATA) : 558 PCA max net quantity (IATA) : 5kg CAO packing instructions (IATA) : 562 CAO max net quantity (IATA) : 25kg Special provisions (IATA) : A3 ERG code (IATA) : 5P
- Inland waterway transport
Classification code (ADN) : OT2 Special provisions (ADN) : 274, 802 Limited quantities (ADN) : 1 kg Excepted quantities (ADN) : E2 Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 2
- Rail transport
Classification code (RID) : OT2 Special provisions (RID) : 274 Excepted quantities (RID) : E2 Packing instructions (RID) : P002, IBC06 Mixed packing provisions (RID) : MP2 Portable tank and bulk container instructions (RID) : T3 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAN Special provisions for RID tanks (RID) : TU3 Transport category (RID) : 2 Special provisions for carriage – Packages (RID) : W11 Special provisions for carriage - Loading, unloading and handling (RID) : CW24, CW28 Colis express (express parcels) (RID) : CE10 Hazard identification number (RID) : 56
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions Cadmium nitrate is on the REACH Candidate List CADMIUM NITRATE TETRAHYDRATE Extra Pure is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed SZW-lijst van mutagene stoffen : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : The substance is not listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements: Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1 Ox. Sol. 2 Oxidising Solids, Category 2 H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H312 Harmful in contact with skin. H332 Harmful if inhaled. H410 Very toxic to aquatic life with long lasting effects. R20 Harmful by inhalation R21 Harmful in contact with skin R22 Harmful if swallowed R45 May cause cancer R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R8 Contact with combustible material may cause fire N Dangerous for the environment O Oxidising Xn Harmful