CADMIUM OXIDE AR

CADMIUM OXIDE AR

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : CADMIUM OXIDE AR
Catalogue No. : AL1035 Product form : Substance
CAS Number : 1306-19-0 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 28259020
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (inhal.),
Category 2
H330
Germ cell mutagenicity,
Category 2
H341
Carcinogenicity, Category
1A
H350
Reproductive toxicity,
Category 2
H361fd
Specific target organ
toxicity Repeated
exposure, Category 1
H372
Hazardous to the aquatic
environment Chronic
Hazard, Category 1
H410
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.1; R45
Muta.Cat.3; R68
Repr.Cat.3; R62
Repr.Cat.3; R63
T+; R26
T; R48/23/25
N; R50/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS06GHS06 GHS08GHS08 GHS09GHS09
Signal word (CLP) : Danger
Hazard statements (CLP) : H330 - Fatal if inhaled.
H341 - Suspected of causing genetic defects.
H350 - May cause cancer.
H361fd - Suspected of damaging fertility. Suspected of damaging the unborn child.
H372 - Causes damage to organs through prolonged or repeated exposure.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P260 - Do not breathe vapours, dust, fume, gas.
P273 - Avoid release to the environment.
P281 - Use personal protective equipment as required.
P284 - Wear respiratory protection.
P310 - Immediately call a POISON CENTER/doctor
2.3 Other hazards
Other hazards : This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients

3.1. Substance
Name : CADMIUM OXIDE AR
CAS No. : 1306-19-0
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing.
First-aid measures after skin contact : Gently wash with plenty of soap and water.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously
with water for several minutes.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/effects : May damage fertility. Suspected of damaging the unborn child. Causes damage to
organs through prolonged or repeated exposure.
Symptoms/effects after inhalation : Fatal if inhaled.
Symptoms/effects after ingestion : Harmful if swallowed.
Chronic symptoms : May cause cancer.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as
possible. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 128.41 g/mol
Colour : Dark brown.
Odour : odourless.
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 950 °C
Freezing point : No data available
Boiling point : 1559 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Density : 8.15 g/cm3
Solubility : Water: Insoluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Air contact. Direct sunlight. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Inhalation: Fatal if inhaled.
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : May cause cancer.
STOT-single exposure : Not classified
STOT-repeated exposure : Causes damage to organs through prolonged or repeated exposure.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : Ecology - water : Very toxic to aquatic life with long lasting effects.
12.2 Persistence - degradability
Persistence - degradability : CADMIUM OXIDE AR (1306-19-0) Persistence and degradability May cause long-term adverse effects in the environment.
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
CADMIUM OXIDE AR (1306-19-0)
This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2570
UN-No. (IMDG) : 2570
UN-No. (IATA) : 2570
UN-No. (ADN) : 2570
UN-No. (RID) : 2570
14.2. UN proper shipping name
Proper Shipping Name (ADR) : CADMIUM COMPOUND
Proper Shipping Name (IMDG) : CADMIUM COMPOUND
Proper Shipping Name (IATA) : CADMIUM COMPOUND
Proper Shipping Name (ADN) : CADMIUM COMPOUND
Proper Shipping Name (RID) : CADMIUM COMPOUND
Transport document description (ADR) : UN 2570, CADMIUM COMPOUND, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) : UN 2570, CADMIUM COMPOUND, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) : UN 2570, CADMIUM COMPOUND, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 2570, CADMIUM COMPOUND, 6.1, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 2570, CADMIUM COMPOUND, 6.1, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 6.1
Danger labels : 6.1
IMDG
Transport hazard class(es) : 6.1
Danger labels : 6.1
IATA
Transport hazard class(es) : 6.1
Danger labels : 6.1
ADN
Transport hazard class(es) : 6.1
Danger labels : 6.1
RID
Transport hazard class(es) : 6.1
Danger labels : 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : T5
Special provisions (ADR) : 274, 596
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container
instructions (ADR)
: T1
Portable tank and bulk container special
provisions (ADR)
: TP33
Tank code (ADR) : SGAH, L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Bulk
(ADR)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S9
Hazard identification number (Kemler No.) : 60
Orange plates :
Tunnel restriction code (ADR) : E
EAC code : 2X
- Transport by sea
Special provisions (IMDG) : 223, 274
Packing instructions (IMDG) : P002, LP02
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
Properties and observations (IMDG) : Powder or crystals with various colours. May be soluble or insoluble in water. Toxic if
swallowed, by skin contact or by dust inhalation.
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y645
PCA limited quantity max net quantity
(IATA)
: 10kg
PCA packing instructions (IATA) : 670
PCA max net quantity (IATA) : 100kg
CAO packing instructions (IATA) : 677
CAO max net quantity (IATA) : 200kg
Special provisions (IATA) : A3, A5
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T5
Special provisions (ADN) : 274, 596, 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T5
Special provisions (RID) : 274, 596
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container
instructions (RID)
: T1
Portable tank and bulk container special
provisions (RID)
: TP33
Tank codes for RID tanks (RID) : SGAH, L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Bulk
(RID)
: VC1, VC2, AP7
Special provisions for carriage - Loading,
unloading and handling (RID)
: CW13, CW28, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
Cadmium oxide is on the REACH Candidate List
CADMIUM OXIDE AR is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to
AwSV; ID No. 8660)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : CADMIUM OXIDE AR is listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen-
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen- Ontwikkeling
: The substance is not listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Acute Tox. 2 (Inhalation) Acute toxicity (inhal.), Category 2
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Carc. 1A Carcinogenicity, Category 1A
Muta. 2 Germ cell mutagenicity, Category 2
Repr. 2 Reproductive toxicity, Category 2
STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1
H330 Fatal if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
R26 Very toxic by inhalation
R45 May cause cancer
R48/23/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation and if
swallowed
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment
R62 Possible risk of impaired fertility
R63 Possible risk of harm to the unborn child
R68 Possible risk of irreversible effects
N Dangerous for the environment
T Toxic
T+ Very toxic