BALSAM CANADA Synthetic

BALSAM CANADA Synthetic

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : BALSAM CANADA (synthetic)
Catalogue No. : AL0530 Product form : Mixture
CAS Number : 8007-47-4 EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 13012000
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Laboratory chemicals, Manufacture of substances
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Flammable liquids,
Category 3
H226
Acute toxicity (dermal),
Category 4
H312
Acute toxicity (inhal.),
Category 4
H332
Skin corrosion/irritation,
Category 2
H315
Full text of classification categories and H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS07GHS07
Signal word (CLP) : Warning
Hazard statements (CLP) : H226 - Flammable liquid and vapour
H312+H332 - Harmful in contact with skin or if inhaled
H315 - Causes skin irritation
Precautionary statements (CLP) : P280 - Wear protective gloves, protective clothing, eye protection, face protection
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
CAS No. : 8007-47-4
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
Xylene (CAS No) 1330-20-7 (EC no) 215-535-7 (EC index no) 601-022-00-9 50 - 75 Flam. Liq. 3, H226 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 STOT SE 3, H335
Dibutyl phthalate substance listed as REACH Candidate (Dibutyl phthalate (DBP)) substance listed in REACH Annex XIV (Dibutyl phthalate (DBP)) (CAS No) 84-74-2 (EC no) 201-557-4 (EC index no) 607-318-00-4 5 - 10 Repr. 1B, H360D Repr. 2, H361f Aquatic Acute 1, H400
Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Assure fresh air breathing. If breathing is difficult, remove victim to fresh air and keep
at rest in a position comfortable for breathing.
First-aid measures after skin contact : Wash with plenty of water/…. Get immediate medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Foam. Water spray.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures : No additional information available
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : On land, sweep or shovel into suitable containers. Collect spillage.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Do not breathe vapours.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Clear colourless.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : 62 °C
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable liquid and vapour
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
ATE CLP (dermal) 1100 mg/kg bodyweight
ATE CLP (gases) 4500 ppmv/4h
ATE CLP (vapours) 11 mg/l/4h
ATE CLP (dust,mist) 1.5 mg/l/4h
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful in contact with skin.

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
Component
Dibutyl phthalate (84-74-2) This substance/mixture does not meet the PBT criteria of REACH regulation, annex
XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex
XIII
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1307
UN-No. (IMDG) : 1307
UN-No. (IATA) : 1307
UN-No. (ADN) : 1307
UN-No. (RID) : 1307
14.2. UN proper shipping name
Proper Shipping Name (ADR) : XYLENES
Proper Shipping Name (IMDG) : XYLENES
Proper Shipping Name (IATA) : XYLENES
Proper Shipping Name (ADN) : XYLENES
Proper Shipping Name (RID) : XYLENES
Transport document description (ADR) : UN 1307, XYLENES, 3, III
Transport document description (IMDG) : UN 1307, XYLENES, 3, III
Transport document description (IATA) : UN 1307, XYLENES, 3, III
Transport document description (ADN) : UN 1307, XYLENES, 3, III
Transport document description (RID) : UN 1307, XYLENES, 3, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 3
Danger labels : 3
IMDG
Transport hazard class(es) : 3
Danger labels : 3
IATA
Transport hazard class(es) : 3
Danger labels : 3
ADN
Transport hazard class(es) : 3
Danger labels : 3
RID
Transport hazard class(es) : 3
Danger labels : 3
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1
Limited quantities (ADR) : 5L
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P001, IBC03, LP01, R001
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T2
Portable tank and bulk container special
provisions (ADR)
: TP1
Tank code (ADR) : LGBF
Vehicle for tank carriage : FL
Transport category (ADR) : 3
Special provisions for carriage - Packages
(ADR)
: V12
Special provisions for carriage - Operation
(ADR)
: S2
Hazard identification number (Kemler No.) : 30
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : 3YE
- Transport by sea
Special provision (IMDG) : 223
Limited quantities (IMDG) : 5 L
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P001, LP01
IBC packing instructions (IMDG) : IBC03
Tank instructions (IMDG) : T2
Tank special provisions (IMDG) : TP1
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : A
Flash point (IMDG) : 23°C to 30°C c.c.
MFAG-No : 130
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y344
PCA limited quantity max net quantity
(IATA)
: 10L
PCA packing instructions (IATA) : 355
PCA max net quantity (IATA) : 60L
CAO packing instructions (IATA) : 366
CAO max net quantity (IATA) : 220L
Special provision (IATA) : A3
ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F1
Limited quantities (ADN) : 5 L
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EX, A
Ventilation (ADN) : VE01
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : F1
Limited quantities (RID) : 5L
Excepted quantities (RID) : E1
Packing instructions (RID) : P001, IBC03, LP01, R001
Mixed packing provisions (RID) : MP19
Portable tank and bulk container
instructions (RID)
: T2
Portable tank and bulk container special
provisions (RID)
: TP1
Tank codes for RID tanks (RID) : LGBF
Transport category (RID) : 3
Special provisions for carriage – Packages
(RID)
: W12
Colis express (express parcels) (RID) : CE4
Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions
Contains substance on the candidate list in concentration ≥ 0.1% or with a lower specific limit: Dibutyl phthalate (DBP) (EC 201-
557-4, CAS 84-74-2)
Contains REACH Annex XIV substances:
Substance name Authorisation number Sunset date REACH authorization
exemptions
Dibutyl phthalate (DBP) (EC
201-557-4, CAS 84-74-2)
21/01/2015
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water (Classification according to AwSV,
Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to
Denmark
Class for fire hazard : Class III-1
Store unit : 50 liter
Classification remarks : Flammable according to the Danish Ministry of Justice; Emergency management
guidelines for the storage of flammable liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-phrases:
Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Flam. Liq. 3 Flammable liquids, Category 3
Repr. 1B Reproductive toxicity, Category 1B
Repr. 2 Reproductive toxicity, Category 2
Skin Irrit. 2 Skin corrosion/irritation, Category 2
STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation
H226 Flammable liquid and vapour
H312 Harmful in contact with skin
H315 Causes skin irritation
H332 Harmful if inhaled
H335 May cause respiratory irritation
H360D May damage the unborn child
H361f Suspected of damaging fertility
H400 Very toxic to aquatic life