SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	GENTIAN VIOLET SOLUTION
Catalogue No. :	AL2265	Product form :	Mixture
CAS Number :		EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	32041349
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Industrial For professional use only
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :	GHS07 GHS08
Signal word (CLP) :	Warning
Hazard statements (CLP) :	H319 - Causes serious eye irritation. H351 - Suspected of causing cancer. H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements (CLP) :	P273 - Avoid release to the environment. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name	Product identifier	%	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water	(CAS-No.) 7732-18-5 (EC-No.) 231-791-2	75 - 99	Not classified
Ethanol	(CAS-No.) 64-17-5 (EC-No.) 200-578-6 (EC Index-No.) 603-002-00-5	15 - 25	Flam. Liq. 3, H226 Skin Corr. 1A, H314
GENTIAN VIOLET AR	-	1 - 5	Not classified
AMMONIUM OXALATE AR 99.5%	(CAS-No.) 6009-70-7	0.1 - 1	Not classified
Full text of H-statements: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary.
First-aid measures after skin contact :	Gently wash with plenty of soap and water. Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion :	Rinse mouth. Get medical advice/attention. Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/effects after eye contact : Causes serious eye irritation. Chronic symptoms : Suspected carcinogen.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	Treat symptomatically.

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Ventilate area.
6.2 Environmental precautions
Harmful to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures :	Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	Protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	[In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Dark violet solution.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	Flammable liquid and vapour.
Vapour pressure :	17.535 mm Hg (at 20°C)
Relative vapour density at 20°C :	0.62
Density :	1 g/cm3
Solubility :	Water: Soluble in water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified
Skin corrosion/irritation :	Not classified
Serious eye damage/irritation :	Causes serious eye irritation.
Respiratory or skin sensitisation :	Not classified
Germ cell mutagenicity :	Not classified
Carcinogenicity :	Suspected of causing cancer.
STOT-single exposure :	Not classified
STOT-repeated exposure :	Not classified

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.
Additional information :	Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	3082
UN-No. (IMDG) :	3082
UN-No. (IATA) :	3082
UN-No. (ADN) :	3082
UN-No. (RID) :	3082
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (IMDG) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (IATA) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (ADN) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Proper Shipping Name (RID) :	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Transport document description (ADR) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III
Transport document description (IMDG) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III
Transport document description (IATA) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III
Transport document description (ADN) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III
Transport document description (RID) :	UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	9
Danger labels :	9
IMDG
Transport hazard class(es) :	9
Danger labels :	9
IATA
Transport hazard class(es) :	9
Danger labels :	9
ADN
Transport hazard class(es) :	9
Danger labels :	9
RID
Transport hazard class(es) :	9
Danger labels :	9
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : M6 Special provisions (ADR) : 274, 335, 375, 601 Limited quantities (ADR) : 5l Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Special packing provisions (ADR) : PP1 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1, TP29 Tank code (ADR) : LGBV Vehicle for tank carriage : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : - EAC code : •3Z
- Transport by sea
Special provisions (IMDG) : 274, 335, 969 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : LP01, P001 Special packing provisions (IMDG) : PP1 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP2, TP29 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-F Stowage category (IMDG) : A MFAG-No : 171
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y964 PCA limited quantity max net quantity (IATA) : 30kgG PCA packing instructions (IATA) : 964 PCA max net quantity (IATA) : 450L CAO packing instructions (IATA) : 964 CAO max net quantity (IATA) : 450L Special provisions (IATA) : A97, A158, A197 ERG code (IATA) : 9L
- Inland waterway transport
Classification code (ADN) : M6 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : M6 Special provisions (RID) : 274, 335, 375, 601 Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Special packing provisions (RID) : PP1 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1, TP29 Tank codes for RID tanks (RID) : LGBV Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW31 Colis express (express parcels) (RID) : CE8 Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances
15.1.2. National regulations
Germany
Reference to AwSV : Water hazard class (WGK) 3, severe hazard to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : Ethanol is listed SZW-lijst van mutagene stoffen : None of the components are listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Borstvoeding : Ethanol is listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Vruchtbaarheid : Ethanol is listed NIET-limitatieve lijst van voor de voortplanting giftige stoffen- Ontwikkeling : Ethanol is listed
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-statements: Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3 Carc. 2 Carcinogenicity, Category 2 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A H226 Flammable liquid and vapour. H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H412 Harmful to aquatic life with long lasting effects.