GENTIAN VIOLET SOLUTION (Alcoholic) |
Synonyms : |
SECTION 1: Identification of the substance/mixture and of the company/undertaking |
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1.1 Product identifier |
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Chemical Name : | GENTIAN VIOLET SOLUTION (alcoholic solution) | ||
Catalogue No. : | AL2266 | Product form : | Mixture |
CAS Number : | EC Number : | ||
Grade : | EC Index Number : | ||
Chemical Formula : | HSN Code : | 32041349 | |
Synonyms : | |||
Chemical Structure : | |||
1.2 Relevant identified uses of the substance or mixture and uses advised against |
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Use of the substance/mixture : | Industrial. For professional use only. | ||
Uses advised against : | No additional information available | ||
1.3 Details of the supplier of the safety data sheet |
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Company identification : | Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India. |
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1.4 Emergency Contact Details |
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Phone / e-Mail : | Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in |
SECTION 2: Hazards identification |
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2.1 Classification of the substance or mixture |
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Classification according to Regulation (EC) No. 1272/2008 [CLP] | |
Mixture/Substance: SDS EU 2015: According to Annex II of Regulation (EC) No. 453/2010 (REACH Annex II) Flammable liquids, Category 3 H226 Serious eye damage/eye irritation, Category 2 H319 Carcinogenicity, Category 2 H351 Hazardous to the aquatic environment Chronic Hazard, Category 3 H412 Full text of classification categories and H statements : see section 16 |
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Adverse physicochemical, human health and environmental effects | |
No additional information available | |
2.2 Label elements |
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Labelling according to Regulation (EC) No. 1272/2008 [CLP] | |
Hazard pictograms (CLP) : | GHS02 GHS07 GHS08 |
Signal word (CLP) : | Warning |
Hazard statements (CLP) : | H226 - Flammable liquid and vapour H319 - Causes serious eye irritation H351 - Suspected of causing cancer H412 - Harmful to aquatic life with long lasting effects |
Precautionary statements (CLP) : | P273 - Avoid release to the environment P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
2.3 Other hazards |
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Other hazards : | No additional information available |
SECTION 3: Composition/information on ingredients |
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3.1. Substance |
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Not applicable | |||
3.2. Mixture |
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Name | Product identifier | % | Classification according to Regulation (EC) No. 1272/2008 [CLP] |
METHANOL EL (ELECTRONIC Grade) 99.7% | (CAS No) 97-56-1 | >= 99 | Flam. Liq. 2, H225 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Oral), H301 STOT SE 1, H370 |
GENTIAN VIOLET AR | - | 1 - 5 | Not classified |
Full text of H-phrases: see section 16 |
SECTION 4: First aid measures |
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4.1 Description of first aid measures |
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First-aid measures after inhalation : | Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. Get medical advice/attention. |
First-aid measures after skin contact : | Gently wash with plenty of soap and water. Wash contaminated clothing before reuse. Get medical advice/attention. |
First-aid measures after eye contact : | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. |
First-aid measures after ingestion : | Rinse mouth. Get medical advice/attention. Do NOT induce vomiting. |
4.2 Most important symptoms and effects, both acute and delayed |
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Symptoms relating to use : | Symptoms/injuries : May cause cancer. Symptoms/injuries after eye contact : Causes serious eye irritation. |
4.3 Indication of any immediate medical attention and special treatment needed |
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General information : | Treat symptomatically. |
SECTION 5: Fire-fighting measures |
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5.1 Extinguishing media |
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Suitable extinguishing media : | Water spray. Foam. Dry powder. Carbon dioxide. |
Unsuitable extinguishing media : | Do not use a heavy water stream. |
5.2 Special hazards arising from the substance or mixture |
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Fire hazard : | Flammable liquid and vapour. |
Explosion hazard : | May form flammable/explosive vapour-air mixture. |
5.3 Advice for firefighters |
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Protection during firefighting : | Do not enter fire area without proper protective equipment, including respiratory protection. |
SECTION 6: Accidental release measures |
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6.1 Personal precautions, protective equipment and emergency procedures |
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General measures : | Remove ignition sources. No naked lights. No smoking. Use special care to avoid static electric charges. |
6.1.1. For non-emergency personnel |
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Emergency procedures : | Evacuate unnecessary personnel. |
6.1.2. For emergency responders |
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Protective equipment | Use personal protective equipment as required |
Emergency procedures | Ventilate area. |
6.2 Environmental precautions |
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Harmful to aquatic life with long lasting effects. | |
6.3 Methods and material for containment and cleaning up |
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Methods for cleaning up : | Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. |
6.4 Reference to other sections |
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Reference : | No additional information available |
SECTION 7: Handling and storage |
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7.1 Precautions for safe handling |
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Additional hazards when processed : | Handle empty containers with care because residual vapours are flammable. |
Precautions for safe handling : | Keep away from sources of ignition - No smoking. No naked lights. No smoking. Take precautionary measures against static discharge. Avoid contact with skin and eyes. Do not breathe vapours. |
Hygiene measures : | Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. |
7.2 Conditions for safe storage, including any incompatibilities |
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Technical measures : | Proper grounding procedures to avoid static electricity should be followed. |
Storage conditions : | Keep container tightly closed. Keep in fireproof place. |
7.3 Specific end use(s) |
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No additional information available |
SECTION 8: Exposure controls/personal protection |
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8.1 Control parameters |
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No additional information available | |
8.2 Exposure controls |
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Hand protection : | Protective gloves |
Eye protection : | Chemical goggles or safety glasses |
Skin and body protection : | Wear suitable protective clothing |
Respiratory protection : | Where exposure through inhalation may occur from use, respiratory protection equipment is recommended |
SECTION 9: Physical and chemical properties |
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9.1 Information on basic physical and chemical properties |
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Physical state : | Liquid Colour |
Colour : | Dark violet. |
Odour : | characteristic alcoholic odour. |
Odour threshold : | 5100 ppm |
pH value : | No data available |
Relative evaporation rate (butylacetate=1) : | 1.9 |
Melting point : | -110 °C |
Freezing point : | No data available |
Boiling point : | No data available |
Flash point : | 12.5 °C |
Auto-ignition temperature : | 385 °C |
Decomposition temperature : | No data available |
Flammability (solid, gas) : | Flammable |
Vapour pressure : | 12.8 kPa at 20°C |
Relative vapour density at 20°C : | 3 |
Density : | < 1 g/cm3 |
Solubility : | Water: Miscible in water |
Log Pow : | Separates from oil. |
Viscosity, kinematic : | No data available |
Viscosity, dynamic : | No data available |
Explosive properties : | No data available |
Oxidising properties : | No data available |
Explosive limits : | 3.3 - 36.5 vol % |
9.2 Other information |
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No additional information available |
SECTION 10: Stability and reactivity |
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10.1 Reactivity |
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No additional information available | |
10.2 Chemical stability |
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Flammable liquid and vapour. May form flammable/explosive vapour-air mixture. | |
10.3 Possibility of hazardous reactions |
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No additional information available | |
10.4 Conditions to avoid |
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Open flame. Heat. Sparks. Overheating. | |
10.5 Incompatible materials |
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No additional information available | |
10.6 Hazardous decomposition products |
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May release flammable gases. |
SECTION 11: Toxicological information |
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11.1 Information on toxicological effects |
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Acute toxicity : | Not classified |
Skin corrosion/irritation : | Not classified |
Serious eye damage/irritation : | Causes serious eye irritation. |
Respiratory or skin sensitisation : | Not classified |
Germ cell mutagenicity : | Not classified |
Carcinogenicity : | Suspected of causing cancer. |
Reproductive toxicity : | Not classified |
Specific target organ toxicity (single exposure) : | Not classified |
Specific target organ toxicity (repeated exposure) : | Not classified |
SECTION 12: Ecological information |
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12.1 Toxicity |
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Toxicity information : | No additional information available |
12.2 Persistence - degradability |
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Persistence - degradability : | No additional information available |
12.3 Bioaccumulative potential |
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Bioaccumulative potential : | GENTIAN VIOLET ALCOHOLIC SOLUTION FOR STAINING Log Pow Separates from oil. |
12.4 Mobility in soil |
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Mobility in soil : | No additional information available |
12.5 Results of PBT and vPvB assessment |
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No additional information available | |
12.6 Other adverse effects |
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Environmental precautions : | No additional information available |
SECTION 13: Disposal considerations |
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13.1 Waste treatment methods |
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Product/Packaging disposal recommendations : | Dispose of contents/container to ... |
Additional information : | Handle empty containers with care because residual vapours are flammable. |
SECTION 14: Transport information |
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In accordance with ADR / RID / IMDG / IATA / ADN | |
14.1. UN number |
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UN-No. (ADR) : | 1230 |
UN-No. (IMDG) : | 1230 |
UN-No. (IATA) : | 1230 |
UN-No. (ADN) : | 1230 |
UN-No. (RID) : | 1230 |
14.2. UN proper shipping name |
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Proper Shipping Name (ADR) : | METHANOL |
Proper Shipping Name (IMDG) : | METHANOL |
Proper Shipping Name (IATA) : | METHANOL |
Proper Shipping Name (ADN) : | METHANOL |
Proper Shipping Name (RID) : | METHANOL |
Transport document description (ADR) : | UN 1230, METHANOL, 3 (6.1), II |
Transport document description (IMDG) : | UN 1230, METHANOL, 3 (6.1), II |
Transport document description (IATA) : | UN 1230, METHANOL, 3 (6.1), II |
Transport document description (ADN) : | UN 1230, METHANOL, 3 (6.1), II |
Transport document description (RID) : | UN 1230, METHANOL, 3 (6.1), II |
14.3. Transport hazard class(es) |
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ADR | |
Transport hazard class(es) : | 3 (6.1) |
Danger labels : | 3, 6.1 |
IMDG | |
Transport hazard class(es) : | 3 (6.1) |
Danger labels : | 3, 6.1 |
IATA | |
Transport hazard class(es) : | 3 (6.1) |
Danger labels : | 3, 6.1 |
ADN | |
Transport hazard class(es) : | 3 (6.1) |
Danger labels : | 3, 6.1 |
RID | |
Transport hazard class(es) : | 3 (6.1) |
Danger labels : | 3, 6.1 |
14.4. Packing group |
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Packing group (ADR) : | II |
Packing group (IMDG) : | II |
Packing group (IATA) : | II |
Packing group (ADN) : | II |
Packing group (RID) : | II |
14.5. Environmental hazards |
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Dangerous for the environment : | No |
Marine pollutant : | No |
Other information : | No supplementary information available |
14.6. Special precautions for user |
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- Overland transport | |
Classification code (ADR) : FT1 Special provision (ADR) : 279 Limited quantities (ADR) : 1L Excepted quantities (ADR) : E2 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15 Vehicle for tank carriage : FL Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S2, S19 Hazard identification number (Kemler No.) : 336 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •2WE APP code : A(fl) |
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- Transport by sea | |
Special provision (IMDG) : 279 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-D Stowage category (IMDG) : B Stowage and handling (IMDG) : SW2 Flash point (IMDG) : 12°C c.c. MFAG-No : 131 |
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- Air transport | |
PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 352 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provision (IATA) : A104, A113 ERG code (IATA) : 3L |
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- Inland waterway transport | |
Not regulated | |
- Rail transport | |
Not regulated | |
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code |
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Not applicable |
SECTION 15: Regulatory information |
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15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture |
15.1.1 EU-Regulations : |
Contains no substances with Annex XVII restrictions Contains no REACH candidate substance Contains no REACH Annex XIV substances. |
15.1.2. National regulations |
Germany |
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
Denmark |
Class for fire hazard : Class I-1 Store unit : 1 liter Classification remarks : F liquids must be followed Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal |
15.2 Chemical Safety Assessment |
No additional information available |
SECTION 16: Other Information |
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