GENTIAN VIOLET SOLUTION (Alcoholic)

GENTIAN VIOLET SOLUTION (Alcoholic)

Synonyms :

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : GENTIAN VIOLET SOLUTION (alcoholic solution)
Catalogue No. : AL2266 Product form : Mixture
CAS Number : EC Number :
Grade : EC Index Number :
Chemical Formula : HSN Code : 32041349
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial. For professional use only.
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Mixture/Substance: SDS EU 2015: According to Annex II
of Regulation (EC) No. 453/2010 (REACH Annex II)
Flammable liquids,
Category 3
H226
Serious eye damage/eye
irritation, Category 2
H319
Carcinogenicity, Category
2
H351
Hazardous to the aquatic
environment Chronic
Hazard, Category 3
H412
Full text of classification categories and H statements : see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02 GHS07GHS07 GHS08GHS08
Signal word (CLP) : Warning
Hazard statements (CLP) : H226 - Flammable liquid and vapour
H319 - Causes serious eye irritation
H351 - Suspected of causing cancer
H412 - Harmful to aquatic life with long lasting effects
Precautionary statements (CLP) : P273 - Avoid release to the environment
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP]
METHANOL EL (ELECTRONIC Grade) 99.7% (CAS No) 97-56-1 >= 99 Flam. Liq. 2, H225 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Oral), H301 STOT SE 1, H370
GENTIAN VIOLET AR - 1 - 5 Not classified
Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Give oxygen or
artificial respiration if necessary. Get medical advice/attention.
First-aid measures after skin contact : Gently wash with plenty of soap and water. Wash contaminated clothing before
reuse. Get medical advice/attention.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get immediate medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Get medical advice/attention. Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Symptoms/injuries : May cause cancer.
Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray. Foam. Dry powder. Carbon dioxide.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Flammable liquid and vapour.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. No naked lights. No smoking. Use special care to avoid
static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Harmful to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Additional hazards when processed : Handle empty containers with care because residual vapours are flammable.
Precautions for safe handling : Keep away from sources of ignition - No smoking. No naked lights. No smoking. Take precautionary measures against static discharge. Avoid contact with skin and eyes. Do not breathe vapours.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures : Proper grounding procedures to avoid static electricity should be followed.
Storage conditions : Keep container tightly closed. Keep in fireproof place.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Where exposure through inhalation may occur from use, respiratory protection equipment is recommended

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Liquid Colour
Colour : Dark violet.
Odour : characteristic alcoholic odour.
Odour threshold : 5100 ppm
pH value : No data available
Relative evaporation rate (butylacetate=1) : 1.9
Melting point : -110 °C
Freezing point : No data available
Boiling point : No data available
Flash point : 12.5 °C
Auto-ignition temperature : 385 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Flammable
Vapour pressure : 12.8 kPa at 20°C
Relative vapour density at 20°C : 3
Density : < 1 g/cm3
Solubility : Water: Miscible in water
Log Pow : Separates from oil.
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : 3.3 - 36.5 vol %
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Flammable liquid and vapour. May form flammable/explosive vapour-air mixture.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks. Overheating.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
May release flammable gases.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Suspected of causing cancer.
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : GENTIAN VIOLET ALCOHOLIC SOLUTION FOR STAINING Log Pow Separates from oil.
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
Additional information : Handle empty containers with care because residual vapours are flammable.

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1230
UN-No. (IMDG) : 1230
UN-No. (IATA) : 1230
UN-No. (ADN) : 1230
UN-No. (RID) : 1230
14.2. UN proper shipping name
Proper Shipping Name (ADR) : METHANOL
Proper Shipping Name (IMDG) : METHANOL
Proper Shipping Name (IATA) : METHANOL
Proper Shipping Name (ADN) : METHANOL
Proper Shipping Name (RID) : METHANOL
Transport document description (ADR) : UN 1230, METHANOL, 3 (6.1), II
Transport document description (IMDG) : UN 1230, METHANOL, 3 (6.1), II
Transport document description (IATA) : UN 1230, METHANOL, 3 (6.1), II
Transport document description (ADN) : UN 1230, METHANOL, 3 (6.1), II
Transport document description (RID) : UN 1230, METHANOL, 3 (6.1), II
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 3 (6.1)
Danger labels : 3, 6.1
IMDG
Transport hazard class(es) : 3 (6.1)
Danger labels : 3, 6.1
IATA
Transport hazard class(es) : 3 (6.1)
Danger labels : 3, 6.1
ADN
Transport hazard class(es) : 3 (6.1)
Danger labels : 3, 6.1
RID
Transport hazard class(es) : 3 (6.1)
Danger labels : 3, 6.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : FT1
Special provision (ADR) : 279
Limited quantities (ADR) : 1L
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P001, IBC02
Mixed packing provisions (ADR) : MP19
Portable tank and bulk container
instructions (ADR)
: T7
Portable tank and bulk container special
provisions (ADR)
: TP2
Tank code (ADR) : L4BH
Tank special provisions (ADR) : TU15
Vehicle for tank carriage : FL
Transport category (ADR) : 2
Special provisions for carriage - Loading,
unloading and handling (ADR)
: CV13, CV28
Special provisions for carriage - Operation
(ADR)
: S2, S19
Hazard identification number (Kemler No.) : 336
Orange plates :
Tunnel restriction code (ADR) : D/E
EAC code : •2WE
APP code : A(fl)
- Transport by sea
Special provision (IMDG) : 279
Limited quantities (IMDG) : 1 L
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P001
IBC packing instructions (IMDG) : IBC02
Tank instructions (IMDG) : T7
Tank special provisions (IMDG) : TP2
EmS-No. (Fire) : F-E
EmS-No. (Spillage) : S-D
Stowage category (IMDG) : B
Stowage and handling (IMDG) : SW2
Flash point (IMDG) : 12°C c.c.
MFAG-No : 131
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y341
PCA limited quantity max net quantity
(IATA)
: 1L
PCA packing instructions (IATA) : 352
PCA max net quantity (IATA) : 1L
CAO packing instructions (IATA) : 364
CAO max net quantity (IATA) : 60L
Special provision (IATA) : A104, A113
ERG code (IATA) : 3L
- Inland waterway transport
Not regulated
- Rail transport
Not regulated
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions
Contains no REACH candidate substance
Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according
to AwSV, Annex 1)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Class for fire hazard : Class I-1
Store unit : 1 liter
Classification remarks : F ; Emergency management guidelines for the storage of flammable
liquids must be followed
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of H- and EUH-phrases:
Acute Tox. 3 (Dermal) Acute toxicity (dermal), Category 3
Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3
Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3
Aquatic Chronic 3 Hazardous to the aquatic environment — Chronic Hazard, Category 3
Carc. 2 Carcinogenicity, Category 2
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
Flam. Liq. 2 Flammable liquids, Category 2
Flam. Liq. 3 Flammable liquids, Category 3
STOT SE 1 Specific target organ toxicity — single exposure, Category 1
H225 Highly flammable liquid and vapour
H226 Flammable liquid and vapour
H301 Toxic if swallowed
H311 Toxic in contact with skin
H319 Causes serious eye irritation
H331 Toxic if inhaled
H351 Suspected of causing cancer
H370 Causes damage to organs
H412 Harmful to aquatic life with long lasting effects