SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	METHYL VIOLET indicator solution
Catalogue No. :	AL3120	Product form :	Mixture
CAS Number :		EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	32041341
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
C; R35 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name	Product identifier	%	Classification according to Directive 67/548/EEC	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water	(CAS No) 7732-18- 5 (EC no) 231-791-2	75 - 99	Not classified	Not classified
Ethanol	(CAS No) 64-17-5 (EC no) 200-578-6 (EC index no) 603- 002-00-5	15 - 25	C; R35 R10	Flam. Liq. 3, H226 Skin Corr. 1A, H314
CRYSTAL VIOLET AR C.I.No.42555 substance listed as REACH Candidate ([4-[4,4'- bis(dimethylamino) benzhydrylidene]cyclohexa-2,5- dien-1- ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with = 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)])	(CAS No) 548-62-9	1 - 5	Carc.Cat.3; R40 Xn; R22 Xi; R41 Xi; R37 Xi; R38 N; R51/53	Eye Dam. 1, H318 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 STOT SE 3, H335 Aquatic Chronic 4, H413
AMMONIUM OXALATE AR 99.5%	(CAS No) 6009-70- 7	0.1 - 1	Not classified	Not classified
Full text of R- and H-phrases: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after skin contact :	Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after eye contact :	Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
First-aid measures after ingestion :	Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after eye contact : Causes serious eye irritation.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard :
Explosion hazard :
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Toxic to aquatic life with long lasting effects.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact during pregnancy/while nursing.
Hygiene measures :	Wash ... thoroughly after handling.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures :	Comply with applicable regulations.
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or face shield
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Violet solution.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	Water: Miscible with water
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
Thermal decomposition generates : Corrosive vapours.
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
Thermal decomposition generates : Corrosive vapours.

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified Irritation : Not classified Corrosivity : Causes severe burns. Sensitisation : Not classified Repeated dose toxicity : Not classified Carcinogenicity : Not classified Mutagenicity : Not classified Toxicity for re
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :
Germ cell mutagenicity :
Carcinogenicity :

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
Component CRYSTAL VIOLET AR C.I.No.42555 (548-62-9) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	1993
UN-No. (IMDG) :	1993
UN-No. (IATA) :	1993
UN-No. (ADN) :	1993
UN-No. (RID) :	1993
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	FLAMMABLE LIQUID, N.O.S.
Proper Shipping Name (IMDG) :	FLAMMABLE LIQUID, N.O.S.
Proper Shipping Name (IATA) :	FLAMMABLE LIQUID, N.O.S.
Proper Shipping Name (ADN) :	FLAMMABLE LIQUID, N.O.S.
Proper Shipping Name (RID) :	FLAMMABLE LIQUID, N.O.S.
Transport document description (ADR) :	UN 1993, FLAMMABLE LIQUID, N.O.S., 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IMDG) :	UN 1993, FLAMMABLE LIQUID, N.O.S., 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (IATA) :	UN 1993, FLAMMABLE LIQUID, N.O.S., 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) :	UN 1993, FLAMMABLE LIQUID, N.O.S., 3, III ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) :	UN 1993, FLAMMABLE LIQUID, N.O.S., 3, III ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	3
Danger labels :	3
IMDG
Transport hazard class(es) :	3
Danger labels :	3
IATA
Transport hazard class(es) :	3
Danger labels :	3
ADN
Transport hazard class(es) :	3
Danger labels :	3
RID
Transport hazard class(es) :	3
Danger labels :	3
14.4. Packing group
Packing group (ADR) :	III
Packing group (IMDG) :	III
Packing group (IATA) :	III
Packing group (ADN) :	III
Packing group (RID) :	III
14.5. Environmental hazards
Dangerous for the environment :	Yes
Marine pollutant :	Yes
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : F1 Special provision (ADR) : 274, 601, 640E Limited quantities (ADR) : 5L Excepted quantities (ADR) : E1 Packing instructions (ADR) : P001, IBC03, LP01, R001 Mixed packing provisions (ADR) : MP19 Portable tank and bulk container instructions (ADR) : T4 Portable tank and bulk container special provisions (ADR) : TP1, TP29 Tank code (ADR) : LGBF Vehicle for tank carriage : FL Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) : V12 Special provisions for carriage - Operation (ADR) : S2 Hazard identification number (Kemler No.) : 30 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3YE
- Transport by sea
Special provision (IMDG) : 223, 274, 955 Limited quantities (IMDG) : 5 L Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P001, LP01 IBC packing instructions (IMDG) : IBC03 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1, TP29 EmS-No. (Fire) : F-E EmS-No. (Spillage) : S-E Stowage category (IMDG) : A MFAG-No : 127;128
- Air transport
PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y344 PCA limited quantity max net quantity (IATA) : 10L PCA packing instructions (IATA) : 355 PCA max net quantity (IATA) : 60L CAO packing instructions (IATA) : 366 CAO max net quantity (IATA) : 220L Special provision (IATA) : A3 ERG code (IATA) : 3L
- Inland waterway transport
Classification code (ADN) : F1 Special provisions (ADN) : 274, 601, 640E Limited quantities (ADN) : 5 L Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EX, A Ventilation (ADN) : VE01 Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : F1 Special provision (RID) : 274, 601, 640E Limited quantities (RID) : 5L Excepted quantities (RID) : E1 Packing instructions (RID) : P001, IBC03, LP01, R001 Mixed packing provisions (RID) : MP19 Portable tank and bulk container instructions (RID) : T4 Portable tank and bulk container special provisions (RID) : TP1, TP29 Tank codes for RID tanks (RID) : LGBF Transport category (RID) : 3 Special provisions for carriage – Packages (RID) : W12 Colis express (express parcels) (RID) : CE4 Hazard identification number (RID) : 30
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
Contains no substances with Annex XVII restrictions Contains substance on the candidate list in concentration ? 0.1% or with a lower specific limit: [4-[4,4'-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1-ylidene]dimethylammonium chloride (C.I. Basic Violet 3) [with ? 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)] (CAS 548-62-9) Contains no REACH Annex XIV substances.
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposal
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 4 Hazardous to the aquatic environment — Chronic Hazard, Category 4 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 3 Flammable liquids, Category 3 Skin Corr. 1A Skin corrosion/irritation, Category 1A Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H226 Flammable liquid and vapour H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H413 May cause long lasting harmful effects to aquatic life R10 Flammable R22 Harmful if swallowed R35 Causes severe burns R37 Irritating to respiratory system R38 Irritating to skin R40 Limited evidence of a carcinogenic effect R41 Risk of serious damage to eyes R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment C Corrosive N Dangerous for the environment Xi Irritant Xn Harmful