SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Chemical Name :	NIGROSINE stain 10% w/v
Catalogue No. :	AL3244	Product form :	Mixture
CAS Number :		EC Number :
Grade :		EC Index Number :
Chemical Formula :		HSN Code :	32041399
Synonyms :
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture :	Laboratory chemicals, Manufacture of substances
Uses advised against :	No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification :	Address:- 102, B wing, Savgan Heights, RTO Lane, Andheri (W), Mumbai-400 053 Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail :	Phone : +91 22 26317055 Mobile : +91 9820385757 e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC or 1999/45/EC
R43 Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
No labelling applicable
2.3 Other hazards
Other hazards :	No additional information available

SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name	Product identifier	%	Classification according to Directive 67/548/EEC	Classification according to Regulation (EC) No. 1272/2008 [CLP]
Water	(CAS No) 7732-18- 5 (EC no) 231-791-2	>= 99	Not classified	Not classified
Formaldehyde	(CAS No) 50-00-0 (EC no) 200-001-8 (EC index no) 605- 001-00-5	0.01 - 1	Carc.Cat.3; R40 T; R23/24/25 C; R34 Xi; R37 R43	Acute Tox. 2 (Dermal), H310 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Oral), H301 Skin Corr. 1B, H314 Eye Dam. 1, H318 Carc. 2, H351 STOT SE 3, H335 Skin Sens. 1, H317
Full text of R- and H-phrases: see section 16

SECTION 4: First aid measures
4.1 Description of first aid measures
First-aid measures after inhalation :	Remove person to fresh air and keep comfortable for breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek medical advice.
First-aid measures after skin contact :	Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see ... on this label). Wash contaminated clothing before reuse.
First-aid measures after eye contact :	Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion :	Rinse mouth out with water. If you feel unwell, seek medical advice.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use :	Symptoms/injuries after inhalation : May cause an allergic skin reaction.
4.3 Indication of any immediate medical attention and special treatment needed
General information :	No additional information available

SECTION 5: Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media :	dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media :	Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Special procedures :	No additional information available
5.3 Advice for firefighters
Protection during firefighting :	Do not attempt to take action without suitable protective equipment.

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures :	Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment	Use personal protective equipment as required
Emergency procedures	Stop release.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up :	Collect spillage. On land, sweep or shovel into suitable containers.
6.4 Reference to other sections
Reference :	No additional information available

SECTION 7: Handling and storage
7.1 Precautions for safe handling
Precautions for safe handling :	Avoid breathing dust/fume/gas/mist/vapours/spray.
Hygiene measures :	Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions :	Store in a well-ventilated place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection :	protective gloves
Eye protection :	Chemical goggles or safety glasses
Skin and body protection :	Wear suitable protective clothing
Respiratory protection :	Wear respiratory protection

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Physical state :	Liquid Colour
Colour :	Violet coloured solution.
Odour :	odourless.
Odour threshold :	No data available
pH value :	No data available
Relative evaporation rate (butylacetate=1) :	No data available
Melting point :	No data available
Freezing point :	No data available
Boiling point :	No data available
Flash point :	No data available
Auto-ignition temperature :	No data available
Decomposition temperature :	No data available
Flammability (solid, gas) :	No data available
Vapour pressure :	No data available
Relative vapour density at 20°C :	No data available
Solubility :	No data available
Log Pow :	No data available
Viscosity, kinematic :	No data available
Viscosity, dynamic :	No data available
Explosive properties :	No data available
Oxidising properties :	No data available
Explosive limits :	No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity
10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5 Incompatible materials
No additional information available
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity :	Not classified Irritation : Not classified Corrosivity : Not classified Sensitisation : May cause sensitisation by skin contact. Repeated dose toxicity : Not classified Carcinogenicity : Not classified Mutagenicity : Not classified Toxicity for re
Skin corrosion/irritation :
Serious eye damage/irritation :
Respiratory or skin sensitisation :
Germ cell mutagenicity :
Carcinogenicity :

SECTION 12: Ecological information
12.1 Toxicity
Toxicity information :	No additional information available
12.2 Persistence - degradability
Persistence - degradability :	No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential :	No additional information available
12.4 Mobility in soil
Mobility in soil :	No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions :	No additional information available

SECTION 13: Disposal considerations
13.1 Waste treatment methods
Product/Packaging disposal recommendations :	Dispose of contents/container to ...

SECTION 14: Transport information
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) :	Not applicable
UN-No. (IMDG) :	Not applicable
UN-No. (IATA) :	Not applicable
UN-No. (ADN) :	Not applicable
UN-No. (RID) :	Not applicable
14.2. UN proper shipping name
Proper Shipping Name (ADR) :	Not applicable
Proper Shipping Name (IMDG) :	Not applicable
Proper Shipping Name (IATA) :	Not applicable
Proper Shipping Name (ADN) :	Not applicable
Proper Shipping Name (RID) :	Not applicable
Transport document description (ADR) :	Not applicable
Transport document description (IMDG) :	Not applicable
Transport document description (IATA) :	Not applicable
Transport document description (ADN) :	Not applicable
Transport document description (RID) :	Not applicable
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) :	Not applicable
IMDG
Transport hazard class(es) :	Not applicable
IATA
Transport hazard class(es) :	Not applicable
ADN
Transport hazard class(es) :	Not applicable
RID
Transport hazard class(es) :	Not applicable
14.4. Packing group
Packing group (ADR) :	Not applicable
Packing group (IMDG) :	Not applicable
Packing group (IATA) :	Not applicable
Packing group (ADN) :	Not applicable
Packing group (RID) :	Not applicable
14.5. Environmental hazards
Dangerous for the environment :	No
Marine pollutant :	No
Other information :	No supplementary information available
14.6. Special precautions for user
- Overland transport
No data available
- Transport by sea
No data available
- Air transport
No data available
- Inland waterway transport
No data available
- Rail transport
No data available
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions NIGROSINE (WATER SOLUBLE) FOR MICROSCOPY is not on the REACH Candidate List NIGROSINE (WATER SOLUBLE) FOR MICROSCOPY is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to AwSV, Annex 1) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-phrases: Acute Tox. 2 (Dermal) Acute toxicity (dermal), Category 2 Acute Tox. 3 (Inhalation) Acute toxicity (inhal.), Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Carc. 2 Carcinogenicity, Category 2 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Sens. 1 Sensitisation — Skin, category 1 STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H301 Toxic if swallowed H310 Fatal in contact with skin H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H318 Causes serious eye damage H331 Toxic if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R37 Irritating to respiratory system R40 Limited evidence of a carcinogenic effect R43 May cause sensitisation by skin contact C Corrosive T Toxic Xi Irritant