1-HYDROXYBENZOTRIAZOLE ANHYDROUS Extra Pure

1-HYDROXYBENZOTRIAZOLE ANHYDROUS Extra Pure

Synonyms : HOBt

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Chemical Name : 1-HYDROXY BENZOTRIAZOLE (anhydrous)
Catalogue No. : AL2487 Product form : Substance
CAS Number : 2592-95-2 EC Number :
Grade : EC Index Number :
Chemical Formula : C6H5N3O HSN Code : 29339900
Synonyms : HOBt
Chemical Structure :
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Industrial For professional use only
Uses advised against : No additional information available
1.3 Details of the supplier of the safety data sheet
Company identification : Address:- 102, B wing, Savgan Heights, RTO Lane,
Andheri (W), Mumbai-400 053
Maharashtra, India.
1.4 Emergency Contact Details
Phone / e-Mail : Phone : +91 22 26317055
Mobile : +91 9820385757
e-mail : info@alphachemika.co.in

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Flammable solids,
Category 2
H228
Full text of H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
F; R11
R1
R44
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) : GHS02GHS02
Signal word (CLP) : Warning
Hazard statements (CLP) : H228 - Flammable solid.
Precautionary statements (CLP) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
2.3 Other hazards
Other hazards : No additional information available

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
CAS No. : 2592-95-2
Full text of R- and H-phrases: see section 16
3.2. Mixture
Not applicable

SECTION 4: First aid measures

4.1 Description of first aid measures
First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.
First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water,
followed by warm water rinse. Wash with plenty of water/…. Wash contaminated
clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do not induce vomiting. Get medical advice/attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms relating to use : No additional information available
4.3 Indication of any immediate medical attention and special treatment needed
General information : Treat symptomatically.

SECTION 5: Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media : Water spray. Dry powder. Carbon dioxide. Foam.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2 Special hazards arising from the substance or mixture
Fire hazard : Flammable solid.
Explosion hazard : May form flammable/explosive vapour-air mixture.
5.3 Advice for firefighters
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory
protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
General measures : Remove ignition sources. No open flames. No smoking. Use special care to avoid
static electric charges.
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment Use personal protective equipment as required
Emergency procedures Ventilate area.
6.2 Environmental precautions
Avoid release to the environment.
6.3 Methods and material for containment and cleaning up
Methods for cleaning up : Collect spillage. On land, sweep or shovel into suitable containers. Soak up spills
with inert solids, such as clay or diatomaceous earth as soon as possible.
6.4 Reference to other sections
Reference : No additional information available

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Precautions for safe handling : Avoid contact with skin and eyes. Do not breathe vapours. Provide good ventilation in process area to prevent formation of vapour. Keep away from sources of ignition - No smoking.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work.
7.2 Conditions for safe storage, including any incompatibilities
Storage conditions : Keep in fireproof place. Keep container tightly closed.
7.3 Specific end use(s)
No additional information available

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
No additional information available
8.2 Exposure controls
Hand protection : Protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : [In case of inadequate ventilation] wear respiratory protection.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state : Solid
Molecular mass : 135.12 g/mol
Colour : White to off white crystalline.
Odour : No data available
Odour threshold : No data available
pH value : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 156 - 158 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20°C : No data available
Solubility : No data available
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2 Other information
No additional information available

SECTION 10: Stability and reactivity

10.1 Reactivity
No additional information available
10.2 Chemical stability
Stable under normal conditions.
10.3 Possibility of hazardous reactions
No additional information available
10.4 Conditions to avoid
Open flame. Heat. Sparks.
10.5 Incompatible materials
Oxidizing agent. Acids.
10.6 Hazardous decomposition products
No additional information available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified

SECTION 12: Ecological information

12.1 Toxicity
Toxicity information : No additional information available
12.2 Persistence - degradability
Persistence - degradability : No additional information available
12.3 Bioaccumulative potential
Bioaccumulative potential : No additional information available
12.4 Mobility in soil
Mobility in soil : No additional information available
12.5 Results of PBT and vPvB assessment
No additional information available
12.6 Other adverse effects
Environmental precautions : No additional information available

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Additional Info : No additional information available

SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 3380
UN-No. (IMDG) : 3380
UN-No. (IATA) : 3380
UN-No. (ADN) : 3380
UN-No. (RID) : 3380
14.2. UN proper shipping name
Proper Shipping Name (ADR) : DESENSITIZED EXPLOSIVE, SOLID, N.O.S.
Proper Shipping Name (IMDG) : DESENSITIZED EXPLOSIVE, SOLID, N.O.S.
Proper Shipping Name (IATA) : DESENSITIZED EXPLOSIVE, SOLID, N.O.S.
Proper Shipping Name (ADN) : DESENSITIZED EXPLOSIVE, SOLID, N.O.S.
Proper Shipping Name (RID) : DESENSITIZED EXPLOSIVE, SOLID, N.O.S.
Transport document description (ADR) : UN 3380, DESENSITIZED EXPLOSIVE, SOLID, N.O.S., 4.1, I
Transport document description (IMDG) : UN 3380, DESENSITIZED EXPLOSIVE, SOLID, N.O.S., 4.1, I
Transport document description (IATA) : UN 3380, DESENSITIZED EXPLOSIVE, SOLID, N.O.S., 4.1, I
Transport document description (ADN) : UN 3380, DESENSITIZED EXPLOSIVE, SOLID, N.O.S., 4.1, I
Transport document description (RID) : UN 3380, DESENSITIZED EXPLOSIVE, SOLID, N.O.S., 4.1, I
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) : 4.1
Danger labels : 4.1
IMDG
Transport hazard class(es) : 4.1
Danger labels : 4.1
IATA
Transport hazard class(es) : 4.1
Danger labels : 4.1
ADN
Transport hazard class(es) : 4.1
Danger labels : 4.1
RID
Transport hazard class(es) : 4.1
Danger labels : 4.1
14.4. Packing group
Packing group (ADR) : I
Packing group (IMDG) : I
Packing group (IATA) : I
Packing group (ADN) : I
Packing group (RID) : I
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : D
Special provisions (ADR) : 274, 311
Limited quantities (ADR) : 0
Excepted quantities (ADR) : E0
Packing instructions (ADR) : P099
Mixed packing provisions (ADR) : MP2
Transport category (ADR) : 1
Special provisions for carriage - Operation
(ADR)
: S14
Tunnel restriction code (ADR) : B
EAC code : 1W
- Transport by sea
Special provisions (IMDG) : 274, 311
Packing instructions (IMDG) : P099
EmS-No. (Fire) : F-B
EmS-No. (Spillage) : S-J
Stowage category (IMDG) : D
Segregation (IMDG) : SG7, SG30
Properties and observations (IMDG) : Desensitized explosive. Explosive and sensitive to friction in the dry state.May form
extremely sensitive compounds with heavy metals and their salts.
- Air transport
PCA Limited quantities (IATA) : Forbidden
PCA limited quantity max net quantity
(IATA)
: Forbidden
PCA packing instructions (IATA) : Forbidden
PCA max net quantity (IATA) : Forbidden
CAO packing instructions (IATA) : Forbidden
CAO max net quantity (IATA) : Forbidden
Special provisions (IATA) : A133
ERG code (IATA) : 3E
- Inland waterway transport
Classification code (ADN) : D
Special provisions (ADN) : 274, 311
Limited quantities (ADN) : 0
Excepted quantities (ADN) : E0
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 1
- Rail transport
Classification code (RID) : D
Special provisions (RID) : 274, 311
Limited quantities (RID) : 0
Excepted quantities (RID) : E0
Packing instructions (RID) : P099
Mixed packing provisions (RID) : MP2
Transport category (RID) : 1
Special provisions for carriage – Packages
(RID)
: W1
Hazard identification number (RID) : 40
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1 EU-Regulations :
No REACH Annex XVII restrictions
1-HYDROXYBENZOTRIAZOLE ANHYDROUS EXTRA PURE is not on the REACH Candidate List
1-HYDROXYBENZOTRIAZOLE ANHYDROUS EXTRA PURE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV
: Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen : The substance is not listed
SZW-lijst van mutagene stoffen : The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen � Borstvoeding
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen �
Vruchtbaarheid
: The substance is not listed
NIET-limitatieve lijst van voor de
voortplanting giftige stoffen � Ontwikkeling
: The substance is not listed
15.2 Chemical Safety Assessment
No additional information available

SECTION 16: Other Information

Full text of R-, H- and EUH-statements:
Flam. Sol. 2 Flammable solids, Category 2
H228 Flammable solid.
R1 Dep